Dicarbonyls of Carbon and Methylidyne Cations

Jiaye Jin; Lili Zhao; Xiaonan Wu; Wei Li; Yuhong Liu; Diego M. Andrada; Mingfei Zhou; Gernot Frenking

doi:10.1021/acs.jpca.7b00739

Dicarbonyls of Carbon and Methylidyne Cations

Jiaye Jin, Lili Zhao, Xiaonan Wu, Wei Li, Yuhong Liu, Diego M. Andrada, Mingfei Zhou, Gernot Frenking

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

5 引用（Scopus）

摘要

The carbon suboxide cation C₃O₂ ⁺ and the protonated carbon suboxide HC₃O₂ ⁺/DC₃O₂ ⁺ were produced in the gas phase. The vibrational spectra were measured via infrared photodissociation spectroscopy of their argon- or CO-tagged complexes. Spectroscopic evidence combined with state-of-the-art quantum chemical calculations indicate that both cations have a bent C_2v symmetry and can be designated as dicarbonyls of a carbon cation and methylidyne cation, respectively.

源语言	英语
页（从-至）	2903-2910
页数	8
期刊	Journal of Physical Chemistry A
卷	121
期	15
DOI	https://doi.org/10.1021/acs.jpca.7b00739
出版状态	已出版 - 20 4月 2017

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abstract = "The carbon suboxide cation C3O2 + and the protonated carbon suboxide HC3O2 +/DC3O2 + were produced in the gas phase. The vibrational spectra were measured via infrared photodissociation spectroscopy of their argon- or CO-tagged complexes. Spectroscopic evidence combined with state-of-the-art quantum chemical calculations indicate that both cations have a bent C2v symmetry and can be designated as dicarbonyls of a carbon cation and methylidyne cation, respectively.",

author = "Jiaye Jin and Lili Zhao and Xiaonan Wu and Wei Li and Yuhong Liu and Andrada, {Diego M.} and Mingfei Zhou and Gernot Frenking",

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T1 - Dicarbonyls of Carbon and Methylidyne Cations

AU - Jin, Jiaye

AU - Zhao, Lili

AU - Wu, Xiaonan

AU - Li, Wei

AU - Liu, Yuhong

AU - Andrada, Diego M.

AU - Zhou, Mingfei

AU - Frenking, Gernot

PY - 2017/4/20

Y1 - 2017/4/20

N2 - The carbon suboxide cation C3O2 + and the protonated carbon suboxide HC3O2 +/DC3O2 + were produced in the gas phase. The vibrational spectra were measured via infrared photodissociation spectroscopy of their argon- or CO-tagged complexes. Spectroscopic evidence combined with state-of-the-art quantum chemical calculations indicate that both cations have a bent C2v symmetry and can be designated as dicarbonyls of a carbon cation and methylidyne cation, respectively.

AB - The carbon suboxide cation C3O2 + and the protonated carbon suboxide HC3O2 +/DC3O2 + were produced in the gas phase. The vibrational spectra were measured via infrared photodissociation spectroscopy of their argon- or CO-tagged complexes. Spectroscopic evidence combined with state-of-the-art quantum chemical calculations indicate that both cations have a bent C2v symmetry and can be designated as dicarbonyls of a carbon cation and methylidyne cation, respectively.

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U2 - 10.1021/acs.jpca.7b00739

DO - 10.1021/acs.jpca.7b00739

M3 - 文章

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AN - SCOPUS:85020024221

SN - 1089-5639

VL - 121

SP - 2903

EP - 2910

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 15

ER -

Dicarbonyls of Carbon and Methylidyne Cations

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