Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

Wenzhong Yang; Hui Cang; Yongming Tang; Jintang Wang; Yuanxiang Shi

doi:10.1007/s10800-007-9470-6

Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

Wenzhong Yang, Hui Cang, Yongming Tang, Jintang Wang, Yuanxiang Shi

化学与分子工程学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF₄ ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.

源语言	英语
页（从-至）	537-542
页数	6
期刊	Journal of Applied Electrochemistry
卷	38
期	4
DOI	https://doi.org/10.1007/s10800-007-9470-6
出版状态	已出版 - 4月 2008

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title = "Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid",

abstract = "The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF4 ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.",

keywords = "Antimony, Electrodeposition, Ionic liquid, Tetrafluoroborate, Tin",

author = "Wenzhong Yang and Hui Cang and Yongming Tang and Jintang Wang and Yuanxiang Shi",

year = "2008",

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doi = "10.1007/s10800-007-9470-6",

language = "英语",

volume = "38",

pages = "537--542",

journal = "Journal of Applied Electrochemistry",

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TY - JOUR

T1 - Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

AU - Yang, Wenzhong

AU - Cang, Hui

AU - Tang, Yongming

AU - Wang, Jintang

AU - Shi, Yuanxiang

PY - 2008/4

Y1 - 2008/4

N2 - The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF4 ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.

AB - The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF4 ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.

KW - Antimony

KW - Electrodeposition

KW - Ionic liquid

KW - Tetrafluoroborate

KW - Tin

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U2 - 10.1007/s10800-007-9470-6

DO - 10.1007/s10800-007-9470-6

M3 - 文章

AN - SCOPUS:40849118210

SN - 0021-891X

VL - 38

SP - 537

EP - 542

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 4

ER -

Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

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