Enantioselective carbonyl-ene reactions of trifluoropyruvate in ionic liquid via a recyclable indium(III)-pybox complex

Jun Feng Zhao, Boon Hong Tan, Ming Kui Zhu, Teguh Budiono W. Tjan, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

28 引用 (Scopus)

摘要

A highly enantioselective carbonyl-ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)-pybox complex in ionic liquid afforded trifluoromethyl-containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselectivities (up to 98% ee). Notably, this catalytic system can be recycled up to seven cycles.

源语言英语
页(从-至)2085-2088
页数4
期刊Advanced Synthesis and Catalysis
352
11-12
DOI
出版状态已出版 - 2010
已对外发布

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