Facile synthesis of PtPd/SnO                         2                          nanocatalysts with good photo-electrocatalytic property

Bingqian Yang; Yawei Yu; Jianbo Zhang; Lefan Yuan; Jingyuan Qiao; Xiulan Hu

doi:10.1016/j.apsusc.2018.12.002

Facile synthesis of PtPd/SnO ₂ nanocatalysts with good photo-electrocatalytic property

Bingqian Yang, Yawei Yu, Jianbo Zhang, Lefan Yuan, Jingyuan Qiao, Xiulan Hu

材料科学与工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

21 引用（Scopus）

摘要

PtPd/SnO ₂ nanocatalysts were synthesized by a simple one-step way of plasma technique in an aqueous solution of tin(II) chloride by using Pt and Pd metal wire as the electrode pair. PtPd/SnO ₂ /GNs composite catalysts were prepared by an ultrasonic mixing PtPd/SnO ₂ with GNs (GNs, graphene nanosheets). The PtPd/SnO ₂ /GNs composite catalysts exhibit a significantly enhanced electrocatalytic performance, cycling stability and CO-poisoning tolerance towards methanol oxidation both under acidic and alkaline condition, which attributed to the synergism of PtPd alloy and SnO ₂ . What's more, the current density of PtPd/SnO ₂ /GNs composite catalyst was obviously improved under light illumination, with 10,029 mA mg _Pt ⁻¹ which was about 1.3 times higher than that without light illumination under alkaline condition. The novel one-step plasma technique could provide a useful approach for fabricating other highly efficient electrocatalysts.

源语言	英语
页（从-至）	263-272
页数	10
期刊	Applied Surface Science
卷	471
DOI	https://doi.org/10.1016/j.apsusc.2018.12.002
出版状态	已出版 - 31 3月 2019

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10.1016/j.apsusc.2018.12.002

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@article{6d54e52c2c2b46d4968fcb25860a165a,

title = " Facile synthesis of PtPd/SnO 2 nanocatalysts with good photo-electrocatalytic property ",

abstract = " PtPd/SnO 2 nanocatalysts were synthesized by a simple one-step way of plasma technique in an aqueous solution of tin(II) chloride by using Pt and Pd metal wire as the electrode pair. PtPd/SnO 2 /GNs composite catalysts were prepared by an ultrasonic mixing PtPd/SnO 2 with GNs (GNs, graphene nanosheets). The PtPd/SnO 2 /GNs composite catalysts exhibit a significantly enhanced electrocatalytic performance, cycling stability and CO-poisoning tolerance towards methanol oxidation both under acidic and alkaline condition, which attributed to the synergism of PtPd alloy and SnO 2 . What's more, the current density of PtPd/SnO 2 /GNs composite catalyst was obviously improved under light illumination, with 10,029 mA mg Pt −1 which was about 1.3 times higher than that without light illumination under alkaline condition. The novel one-step plasma technique could provide a useful approach for fabricating other highly efficient electrocatalysts.",

keywords = "Methanol electro-oxidation, Nanocomposites, PtPd nano-alloy, SnO nanoparticles, Solution plasma",

author = "Bingqian Yang and Yawei Yu and Jianbo Zhang and Lefan Yuan and Jingyuan Qiao and Xiulan Hu",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2019",

month = mar,

day = "31",

doi = "10.1016/j.apsusc.2018.12.002",

language = "英语",

volume = "471",

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TY - JOUR

T1 - Facile synthesis of PtPd/SnO 2 nanocatalysts with good photo-electrocatalytic property

AU - Yang, Bingqian

AU - Yu, Yawei

AU - Zhang, Jianbo

AU - Yuan, Lefan

AU - Qiao, Jingyuan

AU - Hu, Xiulan

PY - 2019/3/31

Y1 - 2019/3/31

N2 - PtPd/SnO 2 nanocatalysts were synthesized by a simple one-step way of plasma technique in an aqueous solution of tin(II) chloride by using Pt and Pd metal wire as the electrode pair. PtPd/SnO 2 /GNs composite catalysts were prepared by an ultrasonic mixing PtPd/SnO 2 with GNs (GNs, graphene nanosheets). The PtPd/SnO 2 /GNs composite catalysts exhibit a significantly enhanced electrocatalytic performance, cycling stability and CO-poisoning tolerance towards methanol oxidation both under acidic and alkaline condition, which attributed to the synergism of PtPd alloy and SnO 2 . What's more, the current density of PtPd/SnO 2 /GNs composite catalyst was obviously improved under light illumination, with 10,029 mA mg Pt −1 which was about 1.3 times higher than that without light illumination under alkaline condition. The novel one-step plasma technique could provide a useful approach for fabricating other highly efficient electrocatalysts.

AB - PtPd/SnO 2 nanocatalysts were synthesized by a simple one-step way of plasma technique in an aqueous solution of tin(II) chloride by using Pt and Pd metal wire as the electrode pair. PtPd/SnO 2 /GNs composite catalysts were prepared by an ultrasonic mixing PtPd/SnO 2 with GNs (GNs, graphene nanosheets). The PtPd/SnO 2 /GNs composite catalysts exhibit a significantly enhanced electrocatalytic performance, cycling stability and CO-poisoning tolerance towards methanol oxidation both under acidic and alkaline condition, which attributed to the synergism of PtPd alloy and SnO 2 . What's more, the current density of PtPd/SnO 2 /GNs composite catalyst was obviously improved under light illumination, with 10,029 mA mg Pt −1 which was about 1.3 times higher than that without light illumination under alkaline condition. The novel one-step plasma technique could provide a useful approach for fabricating other highly efficient electrocatalysts.

KW - Methanol electro-oxidation

KW - Nanocomposites

KW - PtPd nano-alloy

KW - SnO nanoparticles

KW - Solution plasma

UR - http://www.scopus.com/inward/record.url?scp=85057886407&partnerID=8YFLogxK

U2 - 10.1016/j.apsusc.2018.12.002

DO - 10.1016/j.apsusc.2018.12.002

M3 - 文章

AN - SCOPUS:85057886407

SN - 0169-4332

VL - 471

SP - 263

EP - 272

JO - Applied Surface Science

JF - Applied Surface Science

ER -

Facile synthesis of PtPd/SnO 2 nanocatalysts with good photo-electrocatalytic property

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Facile synthesis of PtPd/SnO ₂ nanocatalysts with good photo-electrocatalytic property