TY - JOUR
T1 - Flexible All-Solid-State Direct Methanol Fuel Cells with High Specific Power Density
AU - Sun, Shanshan
AU - Zhao, Minglin
AU - Wang, Qingwei
AU - Xue, Shujie
AU - Huang, Qinghong
AU - Yu, Nengfei
AU - Wu, Yuping
N1 - Publisher Copyright:
© 2023 Wiley-VCH GmbH.
PY - 2023/3/22
Y1 - 2023/3/22
N2 - It is vital to create flexible batteries as power sources to suit the needs of flexible electronic devices because they are widely employed in wearable and portable electronics. The direct methanol fuel cell (DMFC) is a desirable alternative portable energy source since it is a clean, safe, and high energy density cell. The traditional DMFC in mechanical assembly and its unbending property, however, prevent it from being employed in flexible electrical devices. In this study, the flexible membrane electrode assembly (MEA) with superior electrical conductivity and nanoscale TiC-modified carbon cloth (TiC/CC) is used as supporting layer. Additionally, solid methanol fuels used in the manufacturing of flexible all-solid-state DMFC have the advantages of being tiny, light, and having high energy density. Furthermore, the DMFC's placement and bending angle have little effect on its performance, suggesting that DMFC is appropriate for flexible portable energy. The flexible all-solid-state DMFC's power density can reach 14.06 mW cm−2, and after 50 bends at 60°, its voltage loss can be disregarded. The flexible all-solid DMFC has an energy density that is 777.78 Wh Kg−1 higher than flexible lithium-ion batteries, which is advantageous for the commercialization of flexible electronic products.
AB - It is vital to create flexible batteries as power sources to suit the needs of flexible electronic devices because they are widely employed in wearable and portable electronics. The direct methanol fuel cell (DMFC) is a desirable alternative portable energy source since it is a clean, safe, and high energy density cell. The traditional DMFC in mechanical assembly and its unbending property, however, prevent it from being employed in flexible electrical devices. In this study, the flexible membrane electrode assembly (MEA) with superior electrical conductivity and nanoscale TiC-modified carbon cloth (TiC/CC) is used as supporting layer. Additionally, solid methanol fuels used in the manufacturing of flexible all-solid-state DMFC have the advantages of being tiny, light, and having high energy density. Furthermore, the DMFC's placement and bending angle have little effect on its performance, suggesting that DMFC is appropriate for flexible portable energy. The flexible all-solid-state DMFC's power density can reach 14.06 mW cm−2, and after 50 bends at 60°, its voltage loss can be disregarded. The flexible all-solid DMFC has an energy density that is 777.78 Wh Kg−1 higher than flexible lithium-ion batteries, which is advantageous for the commercialization of flexible electronic products.
KW - TiC-modified carbon cloth
KW - direct methanol fuel cells
KW - flexible all-solid-state devices
KW - flexible packages
KW - solid methanol
UR - http://www.scopus.com/inward/record.url?scp=85146290504&partnerID=8YFLogxK
U2 - 10.1002/smll.202205835
DO - 10.1002/smll.202205835
M3 - 文章
AN - SCOPUS:85146290504
SN - 1613-6810
VL - 19
JO - Small
JF - Small
IS - 12
M1 - 2205835
ER -