@article{663d1ac49a9a42c9b3a3e202bf2ee001,
title = "Heterocumulene Sulfinyl Radical OCNSO",
abstract = "Neutral five-atomic cumulenes formally consisting of two pseudohalogens (e.g., NCO, NNN, NSO) by sharing the central nitrogen atom are exotic species that have been barely studied. Through flash vacuum pyrolysis of CF3S(O)NCO at ca. 1200 K, sulfinyl isocyanate, bearing resonance structures of O=C−N=S=O and O=C=N−S=O, has been generated in the gas phase and subsequently characterized in cryogenic matrices (Ar and N2). Its reversible conformational (syn and anti) interconversion and photodecomposition were observed.",
keywords = "IR spectroscopy, cumulenes, matrix isolation, pseudohalogens, sulfur–nitrogen compounds",
author = "Zhuang Wu and Qifan Liu and Jian Xu and Hailong Sun and Dingqing Li and Chao Song and Andrada, {Diego M.} and Gernot Frenking and Tarek Trabelsi and Francisco, {Joseph S.} and Xiaoqing Zeng",
note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2017",
month = feb,
day = "13",
doi = "10.1002/anie.201611576",
language = "英语",
volume = "56",
pages = "2140--2144",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "8",
}