Hydrothermal synthesis and structure of a new three-dimensional inorganic-organic hybrid polyoxomolybdate based on keggin cluster units

Qi Chen, Chunxiu Cai, Guangpeng Zhou, Yan Xu, Dunru Zhu, Xuefang Zheng

科研成果: 期刊稿件文章同行评审

4 引用 (Scopus)

摘要

A new 3-D inorganic-organic hybrid compound {[Cu(4,4′-bipy)] 3(4,4′-bipy)}[PMo12O40]·2H 2O (1) was hydrothermally synthesized and characterized by IR, TG and X-ray diffraction analysis. Single crystal X-ray diffraction confirms that this compound crystallizes in the triclinic crystal system, space group P-1 with a = 10.9180(11), b = 12.3759(13), c = 13.0264(13) Å, α = 113.3560(10)°, β = 93.8730(10)°, γ = 99.0300(10)°. V = 1579.4(3) A°3, Z = 1. Structural analysis indicates that compound 1 exhibits a three-dimensional structure, in which Keggin anions [PMo 12O40]3- are linked by infinite [Cu(4,4′-bipy)]+n chains through Cu-O, and come into being a 3-D inorganic-organic hybrid open framework. The guest 4,4′-bipy molecules and water molecules are filled in the channel formed by Keggin anions [PMo12O40]3- and [Cu(4,4′-bipy)] +n chains.

源语言英语
页(从-至)1197-1200
页数4
期刊Zeitschrift fur Anorganische und Allgemeine Chemie
634
6-7
DOI
出版状态已出版 - 6月 2008

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