Light-induced synthesis of an octacyanometalate-based three-dimensional bimetallic complex [Mn3Mo2]∞

Yi Guo; Xiu Fen Tang; You Song; Xiao Ming Ren

doi:10.1016/j.inoche.2014.04.010

Light-induced synthesis of an octacyanometalate-based three-dimensional bimetallic complex [Mn₃Mo₂]_∞

Yi Guo, Xiu Fen Tang, You Song, Xiao Ming Ren

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

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摘要

Under light irradiation, (Bu₃NH)₃[Mo ^V(CN)₈]·2H₂O reacting with MnClO ₄·6H₂O and NH₄SCN leads to the formation of a new three-dimensional cyano-bridged bimetallic complex {(NH ₄)₂[Mn^II(CH₃OH)₄][Mn ^II(DMF)]₂[Mo^IV(CN)₈] ₂}_∞ (1). X-ray crystallographic analysis reveals that complex 1 crystallizes in a monoclinic space group and contains two different coordination configurations around Mn^II ions in an asymmetric unit. Specifically, one is six-coordinated while the other is five-coordinated. The magnetic investigation shows that the paramagnetic behavior is only ascribed to Mn^II ions because Mo^V has been reduced into diamagnetic Mo^IV.

源语言	英语
页（从-至）	79-81
页数	3
期刊	Inorganic Chemistry Communications
卷	45
DOI	https://doi.org/10.1016/j.inoche.2014.04.010
出版状态	已出版 - 7月 2014

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10.1016/j.inoche.2014.04.010

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@article{cd619bb8c67142f284d069d7517d5631,

title = "Light-induced synthesis of an octacyanometalate-based three-dimensional bimetallic complex [Mn3Mo2]∞",

abstract = "Under light irradiation, (Bu3NH)3[Mo V(CN)8]·2H2O reacting with MnClO 4·6H2O and NH4SCN leads to the formation of a new three-dimensional cyano-bridged bimetallic complex {(NH 4)2[MnII(CH3OH)4][Mn II(DMF)]2[MoIV(CN)8] 2}∞ (1). X-ray crystallographic analysis reveals that complex 1 crystallizes in a monoclinic space group and contains two different coordination configurations around MnII ions in an asymmetric unit. Specifically, one is six-coordinated while the other is five-coordinated. The magnetic investigation shows that the paramagnetic behavior is only ascribed to MnII ions because MoV has been reduced into diamagnetic MoIV.",

keywords = "Light-induced synthesis, Manganese, Molecular magnetism, Octacyanomolybdate, Three-dimensional",

author = "Yi Guo and Tang, {Xiu Fen} and You Song and Ren, {Xiao Ming}",

year = "2014",

month = jul,

doi = "10.1016/j.inoche.2014.04.010",

language = "英语",

volume = "45",

pages = "79--81",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Light-induced synthesis of an octacyanometalate-based three-dimensional bimetallic complex [Mn3Mo2]∞

AU - Guo, Yi

AU - Tang, Xiu Fen

AU - Song, You

AU - Ren, Xiao Ming

PY - 2014/7

Y1 - 2014/7

N2 - Under light irradiation, (Bu3NH)3[Mo V(CN)8]·2H2O reacting with MnClO 4·6H2O and NH4SCN leads to the formation of a new three-dimensional cyano-bridged bimetallic complex {(NH 4)2[MnII(CH3OH)4][Mn II(DMF)]2[MoIV(CN)8] 2}∞ (1). X-ray crystallographic analysis reveals that complex 1 crystallizes in a monoclinic space group and contains two different coordination configurations around MnII ions in an asymmetric unit. Specifically, one is six-coordinated while the other is five-coordinated. The magnetic investigation shows that the paramagnetic behavior is only ascribed to MnII ions because MoV has been reduced into diamagnetic MoIV.

AB - Under light irradiation, (Bu3NH)3[Mo V(CN)8]·2H2O reacting with MnClO 4·6H2O and NH4SCN leads to the formation of a new three-dimensional cyano-bridged bimetallic complex {(NH 4)2[MnII(CH3OH)4][Mn II(DMF)]2[MoIV(CN)8] 2}∞ (1). X-ray crystallographic analysis reveals that complex 1 crystallizes in a monoclinic space group and contains two different coordination configurations around MnII ions in an asymmetric unit. Specifically, one is six-coordinated while the other is five-coordinated. The magnetic investigation shows that the paramagnetic behavior is only ascribed to MnII ions because MoV has been reduced into diamagnetic MoIV.

KW - Light-induced synthesis

KW - Manganese

KW - Molecular magnetism

KW - Octacyanomolybdate

KW - Three-dimensional

UR - http://www.scopus.com/inward/record.url?scp=84899879130&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2014.04.010

DO - 10.1016/j.inoche.2014.04.010

M3 - 文章

AN - SCOPUS:84899879130

SN - 1387-7003

VL - 45

SP - 79

EP - 81

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Light-induced synthesis of an octacyanometalate-based three-dimensional bimetallic complex [Mn3Mo2]∞

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Light-induced synthesis of an octacyanometalate-based three-dimensional bimetallic complex [Mn₃Mo₂]_∞