Liquid-phase oxidative carbonylation of methanol catalysed by Cu-based complex

Yang Yang; Xiaoqin Liu; Dinghua Liu; Huqing Yao

Liquid-phase oxidative carbonylation of methanol catalysed by Cu-based complex

Yang Yang, Xiaoqin Liu, Dinghua Liu, Huqing Yao

化工学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A Cu-based complex catalyst (CuBr_nL_m) was prepared, and was used in synthesis of dimethyl carbonate (DMC) by liquid-phase oxidative carbonylation of methanol. Valence states of elements in catalysts before and after carbonylation and their structures were studied. CuBr_nL_m catalyst was stable after being used for five cycles. Reaction conditions of this system were studied by means of orthogonal experiments and central composite design with Statistica analysis. Under optimal reaction conditions: 100°-110°C, 3-3.5 MPa, reaction time 4-6 hr and concentration of catalyst in methanol 0.15-0.20 g/mL, conversion of methanol and selectivity to DMC could reach 23 and 96-98%, respectively.

源语言	英语
页（从-至）	619-623
页数	5
期刊	Petrochemical Technology
卷	35
期	7
出版状态	已出版 - 15 7月 2006

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title = "Liquid-phase oxidative carbonylation of methanol catalysed by Cu-based complex",

abstract = "A Cu-based complex catalyst (CuBrnLm) was prepared, and was used in synthesis of dimethyl carbonate (DMC) by liquid-phase oxidative carbonylation of methanol. Valence states of elements in catalysts before and after carbonylation and their structures were studied. CuBrnLm catalyst was stable after being used for five cycles. Reaction conditions of this system were studied by means of orthogonal experiments and central composite design with Statistica analysis. Under optimal reaction conditions: 100°-110°C, 3-3.5 MPa, reaction time 4-6 hr and concentration of catalyst in methanol 0.15-0.20 g/mL, conversion of methanol and selectivity to DMC could reach 23 and 96-98%, respectively.",

keywords = "Central composite design, Complex Catalyst, Copper, Dimethyl carbonate, Methanol, Orthogonal design, Oxidative carbonylation",

author = "Yang Yang and Xiaoqin Liu and Dinghua Liu and Huqing Yao",

year = "2006",

month = jul,

day = "15",

language = "英语",

volume = "35",

pages = "619--623",

journal = "Petrochemical Technology",

issn = "1000-8144",

publisher = "Beijing Research Institute of Chemical Industry",

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TY - JOUR

T1 - Liquid-phase oxidative carbonylation of methanol catalysed by Cu-based complex

AU - Yang, Yang

AU - Liu, Xiaoqin

AU - Liu, Dinghua

AU - Yao, Huqing

PY - 2006/7/15

Y1 - 2006/7/15

N2 - A Cu-based complex catalyst (CuBrnLm) was prepared, and was used in synthesis of dimethyl carbonate (DMC) by liquid-phase oxidative carbonylation of methanol. Valence states of elements in catalysts before and after carbonylation and their structures were studied. CuBrnLm catalyst was stable after being used for five cycles. Reaction conditions of this system were studied by means of orthogonal experiments and central composite design with Statistica analysis. Under optimal reaction conditions: 100°-110°C, 3-3.5 MPa, reaction time 4-6 hr and concentration of catalyst in methanol 0.15-0.20 g/mL, conversion of methanol and selectivity to DMC could reach 23 and 96-98%, respectively.

AB - A Cu-based complex catalyst (CuBrnLm) was prepared, and was used in synthesis of dimethyl carbonate (DMC) by liquid-phase oxidative carbonylation of methanol. Valence states of elements in catalysts before and after carbonylation and their structures were studied. CuBrnLm catalyst was stable after being used for five cycles. Reaction conditions of this system were studied by means of orthogonal experiments and central composite design with Statistica analysis. Under optimal reaction conditions: 100°-110°C, 3-3.5 MPa, reaction time 4-6 hr and concentration of catalyst in methanol 0.15-0.20 g/mL, conversion of methanol and selectivity to DMC could reach 23 and 96-98%, respectively.

KW - Central composite design

KW - Complex Catalyst

KW - Copper

KW - Dimethyl carbonate

KW - Methanol

KW - Orthogonal design

KW - Oxidative carbonylation

UR - http://www.scopus.com/inward/record.url?scp=33746771441&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:33746771441

SN - 1000-8144

VL - 35

SP - 619

EP - 623

JO - Petrochemical Technology

JF - Petrochemical Technology

IS - 7

ER -

Liquid-phase oxidative carbonylation of methanol catalysed by Cu-based complex

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