Metal-free synthesis of sulfonylated amides through radical aryl migration-desulfonylation

Jiang Kai Qiu, Wen Juan Hao, Li Fang Kong, Wei Ping, Shu Jiang Tu, Bo Jiang

科研成果: 期刊稿件文章同行评审

24 引用 (Scopus)

摘要

A metal-free arylsulfonyl radical-triggered desulfonylation of N-aryl-N-arylsulfonyl-acrylamides under mild conditions for the facile synthesis of a series of sulfonylated amides has been described. The radical transformation simultaneously installs C-S and C-C bonds with concomitant cleavage of N-S and C-S bonds through continuous 5-exo-trig cyclization, desulfonylation, and aryl migration sequence.

源语言英语
页(从-至)2414-2417
页数4
期刊Tetrahedron Letters
57
22
DOI
出版状态已出版 - 1 6月 2016

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