Molecular and crystal structure of two nickel(II) 1,2-dithiooxalato-S, S′ complexes using 1-(Rbenzyl)pyridinium cation (R = 4′-bromo- 2′-fluoro or 4′-bromo)

Jingli Xie; Xiaoming Ren; Zhaoping Ni; Wenwei Zhang; Yuangen Yao; Qingjin Meng

doi:10.1023/A:1021355901750

Molecular and crystal structure of two nickel(II) 1,2-dithiooxalato-S, S′ complexes using 1-(Rbenzyl)pyridinium cation (R = 4′-bromo- 2′-fluoro or 4′-bromo)

Jingli Xie, Xiaoming Ren, Zhaoping Ni, Wenwei Zhang, Yuangen Yao, Qingjin Meng

科研成果: 期刊稿件 › 文章 › 同行评审

5 引用（Scopus）

摘要

[BrFPy]₂[Ni(dto)₂] (1) and [BrPy]₂[Ni(dto) ₂] (2) complexes have been prepared by reaction of Na ₂[Ni(S₂C₂O₂)₂] and the corresponding 1-(Rbenzyl)pyridinium bromide salt (R₁ = 4′-bromo-2′-fluoro, R₂ = 4′-bromo). The crystallographic data for 1: monoclinic P2₁/c, a = 14.2192(1) Å, b = 14.2533(4) Å, c = 15.6535(3) Å, β = 96.463(1)°, V = 3152.34(11) Å³, Z = 4. Two cations, [Br₁F₁Py]⁺ and [Br₂F ₂Py]⁺, both adopt a conformation where both the aromatic rings are twisted to the corresponding N(1)-C(10)-C(11) or N(2) - C(22) - C(23) reference plane. Data for 2: triclinic P1̄, a = 9.4042(3) Å, b = 9.6814(4) Å, c = 10.3357(4) Å, α = 80.155(1)°, β = 65.245(1)°, γ = 64.259(1)°, V = 769.68(5) Å³, Z = 1. The [Ni(dto)₂]^2- anion exhibits a quasi-planar structure in both complexes. An extensive hydrogen bond network of C-H ⋯ O is clearly observed in 1 and 2, and two complexes show similar crystal packing.

源语言	英语
页（从-至）	65-72
页数	8
期刊	Journal of Chemical Crystallography
卷	33
期	1
DOI	https://doi.org/10.1023/A:1021355901750
出版状态	已出版 - 1月 2003
已对外发布	是

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@article{a9514071b01b421ea689b576816b3b43,

title = "Molecular and crystal structure of two nickel(II) 1,2-dithiooxalato-S, S′ complexes using 1-(Rbenzyl)pyridinium cation (R = 4′-bromo- 2′-fluoro or 4′-bromo)",

abstract = "[BrFPy]2[Ni(dto)2] (1) and [BrPy]2[Ni(dto) 2] (2) complexes have been prepared by reaction of Na 2[Ni(S2C2O2)2] and the corresponding 1-(Rbenzyl)pyridinium bromide salt (R1 = 4′-bromo-2′-fluoro, R2 = 4′-bromo). The crystallographic data for 1: monoclinic P21/c, a = 14.2192(1) {\AA}, b = 14.2533(4) {\AA}, c = 15.6535(3) {\AA}, β = 96.463(1)°, V = 3152.34(11) {\AA}3, Z = 4. Two cations, [Br1F1Py]+ and [Br2F 2Py]+, both adopt a conformation where both the aromatic rings are twisted to the corresponding N(1)-C(10)-C(11) or N(2) - C(22) - C(23) reference plane. Data for 2: triclinic P{\=1}, a = 9.4042(3) {\AA}, b = 9.6814(4) {\AA}, c = 10.3357(4) {\AA}, α = 80.155(1)°, β = 65.245(1)°, γ = 64.259(1)°, V = 769.68(5) {\AA}3, Z = 1. The [Ni(dto)2]2- anion exhibits a quasi-planar structure in both complexes. An extensive hydrogen bond network of C-H ⋯ O is clearly observed in 1 and 2, and two complexes show similar crystal packing.",

keywords = "1-(4′-Bromo-2′-fluorobenzyl)pyridnium, 1-(4′-bromobenzyl) pyridinium, Crystal structure, bis(1,2-dithiooxalato-S,S′)nickelate(II) complex",

author = "Jingli Xie and Xiaoming Ren and Zhaoping Ni and Wenwei Zhang and Yuangen Yao and Qingjin Meng",

year = "2003",

month = jan,

doi = "10.1023/A:1021355901750",

language = "英语",

volume = "33",

pages = "65--72",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer",

number = "1",

}

TY - JOUR

T1 - Molecular and crystal structure of two nickel(II) 1,2-dithiooxalato-S, S′ complexes using 1-(Rbenzyl)pyridinium cation (R = 4′-bromo- 2′-fluoro or 4′-bromo)

AU - Xie, Jingli

AU - Ren, Xiaoming

AU - Ni, Zhaoping

AU - Zhang, Wenwei

AU - Yao, Yuangen

AU - Meng, Qingjin

PY - 2003/1

Y1 - 2003/1

N2 - [BrFPy]2[Ni(dto)2] (1) and [BrPy]2[Ni(dto) 2] (2) complexes have been prepared by reaction of Na 2[Ni(S2C2O2)2] and the corresponding 1-(Rbenzyl)pyridinium bromide salt (R1 = 4′-bromo-2′-fluoro, R2 = 4′-bromo). The crystallographic data for 1: monoclinic P21/c, a = 14.2192(1) Å, b = 14.2533(4) Å, c = 15.6535(3) Å, β = 96.463(1)°, V = 3152.34(11) Å3, Z = 4. Two cations, [Br1F1Py]+ and [Br2F 2Py]+, both adopt a conformation where both the aromatic rings are twisted to the corresponding N(1)-C(10)-C(11) or N(2) - C(22) - C(23) reference plane. Data for 2: triclinic P1̄, a = 9.4042(3) Å, b = 9.6814(4) Å, c = 10.3357(4) Å, α = 80.155(1)°, β = 65.245(1)°, γ = 64.259(1)°, V = 769.68(5) Å3, Z = 1. The [Ni(dto)2]2- anion exhibits a quasi-planar structure in both complexes. An extensive hydrogen bond network of C-H ⋯ O is clearly observed in 1 and 2, and two complexes show similar crystal packing.

AB - [BrFPy]2[Ni(dto)2] (1) and [BrPy]2[Ni(dto) 2] (2) complexes have been prepared by reaction of Na 2[Ni(S2C2O2)2] and the corresponding 1-(Rbenzyl)pyridinium bromide salt (R1 = 4′-bromo-2′-fluoro, R2 = 4′-bromo). The crystallographic data for 1: monoclinic P21/c, a = 14.2192(1) Å, b = 14.2533(4) Å, c = 15.6535(3) Å, β = 96.463(1)°, V = 3152.34(11) Å3, Z = 4. Two cations, [Br1F1Py]+ and [Br2F 2Py]+, both adopt a conformation where both the aromatic rings are twisted to the corresponding N(1)-C(10)-C(11) or N(2) - C(22) - C(23) reference plane. Data for 2: triclinic P1̄, a = 9.4042(3) Å, b = 9.6814(4) Å, c = 10.3357(4) Å, α = 80.155(1)°, β = 65.245(1)°, γ = 64.259(1)°, V = 769.68(5) Å3, Z = 1. The [Ni(dto)2]2- anion exhibits a quasi-planar structure in both complexes. An extensive hydrogen bond network of C-H ⋯ O is clearly observed in 1 and 2, and two complexes show similar crystal packing.

KW - 1-(4′-Bromo-2′-fluorobenzyl)pyridnium

KW - 1-(4′-bromobenzyl) pyridinium

KW - Crystal structure

KW - bis(1,2-dithiooxalato-S,S′)nickelate(II) complex

UR - http://www.scopus.com/inward/record.url?scp=0345871317&partnerID=8YFLogxK

U2 - 10.1023/A:1021355901750

DO - 10.1023/A:1021355901750

M3 - 文章

AN - SCOPUS:0345871317

SN - 1074-1542

VL - 33

SP - 65

EP - 72

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 1

ER -

Molecular and crystal structure of two nickel(II) 1,2-dithiooxalato-S, S′ complexes using 1-(Rbenzyl)pyridinium cation (R = 4′-bromo- 2′-fluoro or 4′-bromo)

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