@article{70df5c9086104966a5f691ae6a159d00,
title = "{"}Naked{"} Ga+ and In+ as pure acceptor ligands: Structure and bonding of [GaPt(GaCp*)4][BAr F]",
abstract = "In the buff: The reaction of [Pt(GaCp*)4] with the Ga + source [Ga2Cp*][BArF] (Cp* = C5Me5; BArF = B{C6H 3(3,5-CF3)2}4) leads to the title complex, which exhibits a naked gallium atom coordinated to a platinum center. DFT calculations reveal that the Ga+ ligand serves as a σ acceptor, and the Pt-Ga bond is additionally supported by strong π interactions. (Figure Presented).",
keywords = "Density functional calculations, Gallium, Group 13 elements, Metalloids, Platinum",
author = "Beatrice Buchin and Christian Gemel and Thomas Cadenbach and Israel Fern{\'a}ndez and Gernot Frenking and Fischer, {Roland A.}",
year = "2006",
month = aug,
day = "4",
doi = "10.1002/anie.200601007",
language = "英语",
volume = "45",
pages = "5207--5210",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "31",
}