One-pot synthesis of potassium-functionalized mesoporous γ-alumina: A solid superbase

Lin Bing Sun; Jing Yang; Jia Hui Kou; Fang Na Gu; Yuan Chun; Ying Wang; Jian Hua Zhu; Zhi Gang Zou

doi:10.1002/anie.200800034

One-pot synthesis of potassium-functionalized mesoporous γ-alumina: A solid superbase

Lin Bing Sun, Jing Yang, Jia Hui Kou, Fang Na Gu, Yuan Chun, Ying Wang, Jian Hua Zhu, Zhi Gang Zou

Nanjing University

科研成果: 期刊稿件 › 文章 › 同行评审

100 引用（Scopus）

摘要

(Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K₂CO ₃ as a pH adjustor and close control of the calcination process (see picture).

源语言	英语
页（从-至）	3418-3421
页数	4
期刊	Angewandte Chemie - International Edition
卷	47
期	18
DOI	https://doi.org/10.1002/anie.200800034
出版状态	已出版 - 21 4月 2008
已对外发布	是

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abstract = "(Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K2CO 3 as a pH adjustor and close control of the calcination process (see picture).",

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T2 - A solid superbase

AU - Sun, Lin Bing

AU - Yang, Jing

AU - Kou, Jia Hui

AU - Gu, Fang Na

AU - Chun, Yuan

AU - Wang, Ying

AU - Zhu, Jian Hua

AU - Zou, Zhi Gang

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N2 - (Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K2CO 3 as a pH adjustor and close control of the calcination process (see picture).

AB - (Graph Presented) Basically super: Potassium-functionalized mesoporous γ-alumina solid superbases that have a high base strength (H_) of 27.0, a well-expressed mesoporous structure, and which are efficient in the isomerization of 1-hexene are synthesized by a one-pot method. The success of this method can be ascribed to the flexible application of K2CO 3 as a pH adjustor and close control of the calcination process (see picture).

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KW - Basicity

KW - Heterogeneous catalysis

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One-pot synthesis of potassium-functionalized mesoporous γ-alumina: A solid superbase

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