TY - JOUR
T1 - Pair Sites on Nodes of Metal-Organic Framework hcp UiO-66 Catalyzetert-Butyl Alcohol Dehydration
AU - Xiao, Yue
AU - Han, Lu
AU - Zhang, Lixiong
AU - Gates, Bruce C.
AU - Yang, Dong
N1 - Publisher Copyright:
© 2021 American Chemical Society
PY - 2021
Y1 - 2021
N2 - On metal oxide cluster nodes of metal-organic frameworks (MOFs), sites not bonded to linkers (e.g., defects and structural vacancies) control reactivity and catalysis. Attention has been focused on isolated, individual sites, but pair sites have been largely overlooked. We now show that the MOFhcpUiO-66, which incorporates dimeric Zr6O8nodes bridged by μ2-OH groups, is an excellent platform for identifying and controlling adjacent sites consisting of OH groups and Zr4+sites, which catalyzetert-butyl alcohol dehydration much more rapidly than isolated single sites.
AB - On metal oxide cluster nodes of metal-organic frameworks (MOFs), sites not bonded to linkers (e.g., defects and structural vacancies) control reactivity and catalysis. Attention has been focused on isolated, individual sites, but pair sites have been largely overlooked. We now show that the MOFhcpUiO-66, which incorporates dimeric Zr6O8nodes bridged by μ2-OH groups, is an excellent platform for identifying and controlling adjacent sites consisting of OH groups and Zr4+sites, which catalyzetert-butyl alcohol dehydration much more rapidly than isolated single sites.
UR - http://www.scopus.com/inward/record.url?scp=85109665618&partnerID=8YFLogxK
U2 - 10.1021/acs.jpclett.1c01574
DO - 10.1021/acs.jpclett.1c01574
M3 - 文章
C2 - 34170689
AN - SCOPUS:85109665618
SN - 1948-7185
VL - 12
SP - 6085
EP - 6089
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
ER -