@article{c4905ca87e0a44fb8366a1d1eac65a6f,
title = "Palladium-Catalyzed Intermolecular Polarity-Mismatched Addition of Unactivated Alkyl Radicals to Unactivated Alkenes",
abstract = "A palladium-catalyzed intermolecular polarity-mismatched addition of unactivated alkyl radicals to unactivated alkenes was developed for the first time. In the two-component dicarbofunctionalization, a variety of primary, secondary, and tertiary unactivated alkyl halides regioselectively reacted with various unactivated olefins. A series of structurally complex heteropolycycles decorated with a quaternary carbon center have been efficiently synthesized.",
keywords = "heteropolycycles, inert C(sp)-C(sp) bond formation, polarity-mismatched radical addition, reverse cascade addition process, unactivated alkenes",
author = "Xiaojin Wu and Guanlin Xiao and Yalan Ding and Ying Zhan and Yao Zhao and Rizhi Chen and Loh, {Teck Peng}",
note = "Publisher Copyright: {\textcopyright} 2020 American Chemical Society.",
year = "2020",
month = dec,
day = "4",
doi = "10.1021/acscatal.0c04013",
language = "英语",
volume = "10",
pages = "14107--14116",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "23",
}