Pure-Supramolecular-Linker Approach to Highly Connected Metal-Organic Frameworks for CO2 Capture

Xiaohui Song; Mingxing Zhang; Cong Chen; Jingui Duan; Wenwei Zhang; Yi Pan; Junfeng Bai

doi:10.1021/jacs.9b07422

Pure-Supramolecular-Linker Approach to Highly Connected Metal-Organic Frameworks for CO₂ Capture

Xiaohui Song, Mingxing Zhang, Cong Chen, Jingui Duan, Wenwei Zhang, Yi Pan, Junfeng Bai

化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

61 引用（Scopus）

摘要

A pure-supramolecular-linker (PSL) approach for the formation of metal-organic frameworks (MOFs) was initially given, which was demonstrated by syntheses of two highly connected and isostructural MOFs, {Fe₃O(TPBTM^6-)(Cl)(H₂O)₂}_∞ (TPBTM = N,N′,N″-Tris(isophthalyl)-1,3,5-benzenetricarboxamide) (NJU-Bai52, NJU-Bai for Nanjing University Bai group) and {Sc₃O(TPBTM^6-)(OH)(H₂O)₂}_∞ (NJU-Bai53). Very interestingly, they exhibit exceptional thermal stability, water stability, and highly selective CO₂ capture properties. In particular, NJU-Bai53 with higher uptakes (2.74 wt % at 0.4 mbar and 298 K, 7.67 wt % at 298 K and 0.15 bar) and higher selectivity may be an excellent candidate for CO₂ capture.

源语言	英语
页（从-至）	14539-14543
页数	5
期刊	Journal of the American Chemical Society
卷	141
期	37
DOI	https://doi.org/10.1021/jacs.9b07422
出版状态	已出版 - 18 9月 2019

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title = "Pure-Supramolecular-Linker Approach to Highly Connected Metal-Organic Frameworks for CO2 Capture",

abstract = "A pure-supramolecular-linker (PSL) approach for the formation of metal-organic frameworks (MOFs) was initially given, which was demonstrated by syntheses of two highly connected and isostructural MOFs, \{Fe3O(TPBTM6-)(Cl)(H2O)2\}∞ (TPBTM = N,N′,N″-Tris(isophthalyl)-1,3,5-benzenetricarboxamide) (NJU-Bai52, NJU-Bai for Nanjing University Bai group) and \{Sc3O(TPBTM6-)(OH)(H2O)2\}∞ (NJU-Bai53). Very interestingly, they exhibit exceptional thermal stability, water stability, and highly selective CO2 capture properties. In particular, NJU-Bai53 with higher uptakes (2.74 wt \% at 0.4 mbar and 298 K, 7.67 wt \% at 298 K and 0.15 bar) and higher selectivity may be an excellent candidate for CO2 capture.",

author = "Xiaohui Song and Mingxing Zhang and Cong Chen and Jingui Duan and Wenwei Zhang and Yi Pan and Junfeng Bai",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

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T1 - Pure-Supramolecular-Linker Approach to Highly Connected Metal-Organic Frameworks for CO2 Capture

AU - Song, Xiaohui

AU - Zhang, Mingxing

AU - Chen, Cong

AU - Duan, Jingui

AU - Zhang, Wenwei

AU - Pan, Yi

AU - Bai, Junfeng

PY - 2019/9/18

Y1 - 2019/9/18

N2 - A pure-supramolecular-linker (PSL) approach for the formation of metal-organic frameworks (MOFs) was initially given, which was demonstrated by syntheses of two highly connected and isostructural MOFs, {Fe3O(TPBTM6-)(Cl)(H2O)2}∞ (TPBTM = N,N′,N″-Tris(isophthalyl)-1,3,5-benzenetricarboxamide) (NJU-Bai52, NJU-Bai for Nanjing University Bai group) and {Sc3O(TPBTM6-)(OH)(H2O)2}∞ (NJU-Bai53). Very interestingly, they exhibit exceptional thermal stability, water stability, and highly selective CO2 capture properties. In particular, NJU-Bai53 with higher uptakes (2.74 wt % at 0.4 mbar and 298 K, 7.67 wt % at 298 K and 0.15 bar) and higher selectivity may be an excellent candidate for CO2 capture.

AB - A pure-supramolecular-linker (PSL) approach for the formation of metal-organic frameworks (MOFs) was initially given, which was demonstrated by syntheses of two highly connected and isostructural MOFs, {Fe3O(TPBTM6-)(Cl)(H2O)2}∞ (TPBTM = N,N′,N″-Tris(isophthalyl)-1,3,5-benzenetricarboxamide) (NJU-Bai52, NJU-Bai for Nanjing University Bai group) and {Sc3O(TPBTM6-)(OH)(H2O)2}∞ (NJU-Bai53). Very interestingly, they exhibit exceptional thermal stability, water stability, and highly selective CO2 capture properties. In particular, NJU-Bai53 with higher uptakes (2.74 wt % at 0.4 mbar and 298 K, 7.67 wt % at 298 K and 0.15 bar) and higher selectivity may be an excellent candidate for CO2 capture.

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M3 - 文章

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SN - 0002-7863

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ER -

Pure-Supramolecular-Linker Approach to Highly Connected Metal-Organic Frameworks for CO2 Capture

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Pure-Supramolecular-Linker Approach to Highly Connected Metal-Organic Frameworks for CO₂ Capture