Regioselective Wacker-Type Oxidation of Internal Olefins in tBuOH Using Oxygen as the Sole Oxidant and tBuONO as the Organic Redox Cocatalyst

Qing Huang, Ya Wei Li, Xiao Shan Ning, Guo Qing Jiang, Xiao Wei Zhang, Jian Ping Qu, Yan Biao Kang

科研成果: 期刊稿件文章同行评审

21 引用 (Scopus)

摘要

A regioselective Wacker-Tsuji oxidation of internal olefins in tBuOH has been developed using oxygen as the terminal oxidant and tert-butyl nitrite as the simple organic redox cocatalyst without the involvement of hazardous cocatalysts or harsh reaction conditions. A series of internal olefins bearing various functional groups can be oxidized to the corresponding substituted ketones in generally good yields with high regioselectivities.

源语言英语
页(从-至)965-969
页数5
期刊Organic Letters
22
3
DOI
出版状态已出版 - 7 2月 2020

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