TY - JOUR
T1 - Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes
T2 - Efficient access to (Z, E)-dienamides
AU - Zhang, Jian
AU - Loh, Teck Peng
PY - 2012/10/22
Y1 - 2012/10/22
N2 - Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route for the synthesis of (Z, E)-dienamides in excellent yields with good stereoselectivity. The catalytic systems allowed oxidative olefination of a wide range of alkenes bearing different functional groups, such as CO2R, COMe, SO2Ph, aryl, CONHBn, CN, PO(OEt)2, as well as Weinreb amide.
AB - Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route for the synthesis of (Z, E)-dienamides in excellent yields with good stereoselectivity. The catalytic systems allowed oxidative olefination of a wide range of alkenes bearing different functional groups, such as CO2R, COMe, SO2Ph, aryl, CONHBn, CN, PO(OEt)2, as well as Weinreb amide.
UR - http://www.scopus.com/inward/record.url?scp=84868014063&partnerID=8YFLogxK
U2 - 10.1039/c2cc36137j
DO - 10.1039/c2cc36137j
M3 - 文章
C2 - 23069732
AN - SCOPUS:84868014063
SN - 1359-7345
VL - 48
SP - 11232
EP - 11234
JO - Chemical Communications
JF - Chemical Communications
IS - 91
ER -