Side-On Bonded Beryllium Dinitrogen Complexes

Guohai Deng, Sudip Pan, Guanjun Wang, Lili Zhao, Mingfei Zhou, Gernot Frenking

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60 引用 (Scopus)

摘要

The preparation and spectroscopic identification of the complexes NNBe(η2-N2) and (NN)2Be(η2-N2) and the energetically higher lying isomers Be(NN)2 and Be(NN)3 are reported. NNBe(η2-N2) and (NN)2Be(η2-N2) are the first examples of covalently side-on bonded N2 adducts of a main-group element. The analysis of the electronic structure using modern methods of quantum chemistry suggests that NNBe(η2-N2) and (NN)2Be(η2-N2) should be classified as π complexes rather than metalladiazirines.

源语言英语
页(从-至)10603-10609
页数7
期刊Angewandte Chemie - International Edition
59
26
DOI
出版状态已出版 - 22 6月 2020

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