Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature

Lu Zhai; Wen Wei Zhang; Jing Lin Zuo; Xiao Ming Ren

doi:10.1039/c6dt02359b

Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature

Lu Zhai, Wen Wei Zhang, Jing Lin Zuo, Xiao Ming Ren

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

26 引用（Scopus）

摘要

A highly thermally stable CP/MOF, comprised of Mg²⁺ and H₂EBTC^2- with the formula of [Mg(H₂EBTC)(DMF)₂], emits dual band luminescence centered at 376 and 555 nm. The former is assigned to the fluorescence of H₂EBTC^2- and the latter with 1.63 μs decay lifetime and large Stokes shifts corresponds to the phosphorescence of H₂EBTC^2-. To the best of our knowledge, this is the first time the ligand-based phosphorescence in a CP/MOF without any heavy atom at room temperature has been observed.

源语言	英语
页（从-至）	11935-11938
页数	4
期刊	Dalton Transactions
卷	45
期	30
DOI	https://doi.org/10.1039/c6dt02359b
出版状态	已出版 - 2016

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title = "Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature",

abstract = "A highly thermally stable CP/MOF, comprised of Mg2+ and H2EBTC2- with the formula of [Mg(H2EBTC)(DMF)2], emits dual band luminescence centered at 376 and 555 nm. The former is assigned to the fluorescence of H2EBTC2- and the latter with 1.63 μs decay lifetime and large Stokes shifts corresponds to the phosphorescence of H2EBTC2-. To the best of our knowledge, this is the first time the ligand-based phosphorescence in a CP/MOF without any heavy atom at room temperature has been observed.",

author = "Lu Zhai and Zhang, {Wen Wei} and Zuo, {Jing Lin} and Ren, {Xiao Ming}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6dt02359b",

language = "英语",

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T1 - Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature

AU - Zhai, Lu

AU - Zhang, Wen Wei

AU - Zuo, Jing Lin

AU - Ren, Xiao Ming

PY - 2016

Y1 - 2016

N2 - A highly thermally stable CP/MOF, comprised of Mg2+ and H2EBTC2- with the formula of [Mg(H2EBTC)(DMF)2], emits dual band luminescence centered at 376 and 555 nm. The former is assigned to the fluorescence of H2EBTC2- and the latter with 1.63 μs decay lifetime and large Stokes shifts corresponds to the phosphorescence of H2EBTC2-. To the best of our knowledge, this is the first time the ligand-based phosphorescence in a CP/MOF without any heavy atom at room temperature has been observed.

AB - A highly thermally stable CP/MOF, comprised of Mg2+ and H2EBTC2- with the formula of [Mg(H2EBTC)(DMF)2], emits dual band luminescence centered at 376 and 555 nm. The former is assigned to the fluorescence of H2EBTC2- and the latter with 1.63 μs decay lifetime and large Stokes shifts corresponds to the phosphorescence of H2EBTC2-. To the best of our knowledge, this is the first time the ligand-based phosphorescence in a CP/MOF without any heavy atom at room temperature has been observed.

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SN - 1477-9226

VL - 45

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JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature

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