Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

Wenqin Wang; Li Wang; Xiaochen Dong; Tianxu Sun; Jianfeng Wang

doi:10.1002/app.23721

Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

Wenqin Wang, Li Wang, Xiaochen Dong, Tianxu Sun, Jianfeng Wang

Zhejiang University

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by ¹³C NMR. It was found that the different carriers have slight effect on the composite of copolymer.

源语言	英语
页（从-至）	1574-1577
页数	4
期刊	Journal of Applied Polymer Science
卷	102
期	2
DOI	https://doi.org/10.1002/app.23721
出版状态	已出版 - 15 10月 2006
已对外发布	是

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abstract = "Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by 13C NMR. It was found that the different carriers have slight effect on the composite of copolymer.",

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AU - Wang, Wenqin

AU - Wang, Li

AU - Dong, Xiaochen

AU - Sun, Tianxu

AU - Wang, Jianfeng

PY - 2006/10/15

Y1 - 2006/10/15

N2 - Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by 13C NMR. It was found that the different carriers have slight effect on the composite of copolymer.

AB - Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by 13C NMR. It was found that the different carriers have slight effect on the composite of copolymer.

KW - Copolymerization

KW - Ethylene/1-hexene

KW - Kinetics

KW - Polystyrene-supported metallocene

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JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 2

ER -

Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

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