Study on electrodeposition Ni-W-P alloy for hydrogen production in microbial electrolysis cell

Yuan Xu, Liyong Wang, Yejie Ye, Yingwen Chen, Shemin Zhu, Shubao Shen

科研成果: 期刊稿件文章同行评审

3 引用 (Scopus)

摘要

A new alloy material nickel-tungsten-phosphorus (Ni-W-P) was obtained by electrodeposition. The effects of experimental conditions, such as heat treatment, nickel sulfate concentration, Sodium Tungstate concentration, Sodium hypophosphite concentration, on the catalytic activity of Ni-W-P alloys for hydrogen evolution reaction were systematically studied. The morphology and chemical components of the catalyst were characterized by scanning electron microscopy (SEM) and X-Ray Fluorescence (XRF). The results show that Ni-W-P is an excellent cathodic material for the hydrogen production by microbial electrolysis cell. At an applied voltage of 0.9V, MEC with Ni-W-P cathode obtained a maximum hydrogen production rate of 1.09 m 3/(m 3·d) with current density of 131 A/m 3 and COD removal of 91.2%.

源语言英语
页(从-至)258-263
页数6
期刊Taiyangneng Xuebao/Acta Energiae Solaris Sinica
33
2
出版状态已出版 - 2月 2012

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