Study on synthesis and properties of poly(ferrocenyl nbutylmethylsilane) with unsymmetrical silicon substitution groups

Jian Jun Wang; Li Wang; Tao Chen; Xue Jie Wang; Chi Liang Wang; Xiao Chen Dong; Jin Hu Yang

doi:10.1016/j.eurpolymj.2005.09.029

Study on synthesis and properties of poly(ferrocenyl ⁿbutylmethylsilane) with unsymmetrical silicon substitution groups

Jian Jun Wang, Li Wang, Tao Chen, Xue Jie Wang, Chi Liang Wang, Xiao Chen Dong, Jin Hu Yang

Zhejiang University

科研成果: 期刊稿件 › 文章 › 同行评审

10 引用（Scopus）

摘要

Novel poly(ferrocenylⁿbutylmethylsilane) with unsymmetrical silicon substitution groups [Fe(η-C₅H₄) ₂(SiBuMe)]_n (PFBMS) (6) have been prepared via the thermal ring-opening polymerization (ROP) of the corresponding strained silicon-bridge [1] ferrocenophanes [Fe(η-C₅H₄) ₂(SiBuMe)] (4) and via the nucleophilic substitution of poly(ferrocenylmethylchlorosilane) [Fe(η-C₅H₄) ₂(SiMeCl)]_n (5) with n-butyllithium. Resultant PFBMS was structurally characterized by ¹H NMR and UV/visible spectroscopy. The molecular weights of PFBMS (6) were measured by gel permeation chromatography (GPC) using polystyrene standard, and the solution electrochemical behavior of PFBMS was investigated by cyclic voltammetry (CV).

源语言	英语
页（从-至）	843-848
页数	6
期刊	European Polymer Journal
卷	42
期	4
DOI	https://doi.org/10.1016/j.eurpolymj.2005.09.029
出版状态	已出版 - 4月 2006
已对外发布	是

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10.1016/j.eurpolymj.2005.09.029

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@article{a083f1d8e50f4be9b884f5a417f5b176,

title = "Study on synthesis and properties of poly(ferrocenyl nbutylmethylsilane) with unsymmetrical silicon substitution groups",

abstract = "Novel poly(ferrocenylnbutylmethylsilane) with unsymmetrical silicon substitution groups [Fe(η-C5H4) 2(SiBuMe)]n (PFBMS) (6) have been prepared via the thermal ring-opening polymerization (ROP) of the corresponding strained silicon-bridge [1] ferrocenophanes [Fe(η-C5H4) 2(SiBuMe)] (4) and via the nucleophilic substitution of poly(ferrocenylmethylchlorosilane) [Fe(η-C5H4) 2(SiMeCl)]n (5) with n-butyllithium. Resultant PFBMS was structurally characterized by 1H NMR and UV/visible spectroscopy. The molecular weights of PFBMS (6) were measured by gel permeation chromatography (GPC) using polystyrene standard, and the solution electrochemical behavior of PFBMS was investigated by cyclic voltammetry (CV).",

keywords = "Cyclic voltammetry, PFBMS, Poly(ferrocenylsilanes), UV",

author = "Wang, {Jian Jun} and Li Wang and Tao Chen and Wang, {Xue Jie} and Wang, {Chi Liang} and Dong, {Xiao Chen} and Yang, {Jin Hu}",

year = "2006",

month = apr,

doi = "10.1016/j.eurpolymj.2005.09.029",

language = "英语",

volume = "42",

pages = "843--848",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd",

number = "4",

}

TY - JOUR

T1 - Study on synthesis and properties of poly(ferrocenyl nbutylmethylsilane) with unsymmetrical silicon substitution groups

AU - Wang, Jian Jun

AU - Wang, Li

AU - Chen, Tao

AU - Wang, Xue Jie

AU - Wang, Chi Liang

AU - Dong, Xiao Chen

AU - Yang, Jin Hu

PY - 2006/4

Y1 - 2006/4

N2 - Novel poly(ferrocenylnbutylmethylsilane) with unsymmetrical silicon substitution groups [Fe(η-C5H4) 2(SiBuMe)]n (PFBMS) (6) have been prepared via the thermal ring-opening polymerization (ROP) of the corresponding strained silicon-bridge [1] ferrocenophanes [Fe(η-C5H4) 2(SiBuMe)] (4) and via the nucleophilic substitution of poly(ferrocenylmethylchlorosilane) [Fe(η-C5H4) 2(SiMeCl)]n (5) with n-butyllithium. Resultant PFBMS was structurally characterized by 1H NMR and UV/visible spectroscopy. The molecular weights of PFBMS (6) were measured by gel permeation chromatography (GPC) using polystyrene standard, and the solution electrochemical behavior of PFBMS was investigated by cyclic voltammetry (CV).

AB - Novel poly(ferrocenylnbutylmethylsilane) with unsymmetrical silicon substitution groups [Fe(η-C5H4) 2(SiBuMe)]n (PFBMS) (6) have been prepared via the thermal ring-opening polymerization (ROP) of the corresponding strained silicon-bridge [1] ferrocenophanes [Fe(η-C5H4) 2(SiBuMe)] (4) and via the nucleophilic substitution of poly(ferrocenylmethylchlorosilane) [Fe(η-C5H4) 2(SiMeCl)]n (5) with n-butyllithium. Resultant PFBMS was structurally characterized by 1H NMR and UV/visible spectroscopy. The molecular weights of PFBMS (6) were measured by gel permeation chromatography (GPC) using polystyrene standard, and the solution electrochemical behavior of PFBMS was investigated by cyclic voltammetry (CV).

KW - Cyclic voltammetry

KW - PFBMS

KW - Poly(ferrocenylsilanes)

KW - UV

UR - http://www.scopus.com/inward/record.url?scp=33644780815&partnerID=8YFLogxK

U2 - 10.1016/j.eurpolymj.2005.09.029

DO - 10.1016/j.eurpolymj.2005.09.029

M3 - 文章

AN - SCOPUS:33644780815

SN - 0014-3057

VL - 42

SP - 843

EP - 848

JO - European Polymer Journal

JF - European Polymer Journal

IS - 4

ER -

Study on synthesis and properties of poly(ferrocenyl nbutylmethylsilane) with unsymmetrical silicon substitution groups

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Study on synthesis and properties of poly(ferrocenyl ⁿbutylmethylsilane) with unsymmetrical silicon substitution groups