Syntheses, structures and magnetic properties of heterobimetallic complexes based on a new tetracyanometalate precursor

Ling Chen Kang; Xin Chen; Cai Feng Wang; Xin Hui Zhou; Jing Lin Zuo; Xiao Zeng You

doi:10.1016/j.ica.2009.09.027

Syntheses, structures and magnetic properties of heterobimetallic complexes based on a new tetracyanometalate precursor

Ling Chen Kang, Xin Chen, Cai Feng Wang, Xin Hui Zhou, Jing Lin Zuo, Xiao Zeng You

Nanjing University

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15 引用（Scopus）

摘要

A new mononuclear tetracyanometallic complex, (n-Bu₄N)[(dbphen)Fe(CN)₄] (1, dbphen = 5,6-dibromo-1,10-phenanthroline), has been prepared by reacting [(dbphen)Fe^II(py)₂(SCN)₂] and KCN in water and further oxidized with chlorine. With the use of 1 as building block, two trinuclear Fe₂M complexes, [(dbphen)₂Fe₂(CN)₈Cu(Me₃tacn )]·3H₂O (2), [(dbphen)₂Fe₂(CN)₈Ni(dabhctd)]·2 H₂O (3) and a chain complex of squares [(dbphen)₂Fe₂(CN)₈Co(MeOH)₂] _n (4), have been synthesized and structurally characterized. Magnetic studies show ferromagnetic coupling between Fe^III and M^II (M = Cu, 2; Ni, 3) ions bridged by cyanides in complexes 2 and 3, while complex 4 exhibits meta-magnetic behavior.

源语言	英语
页（从-至）	5195-5202
页数	8
期刊	Inorganica Chimica Acta
卷	362
期	15
DOI	https://doi.org/10.1016/j.ica.2009.09.027
出版状态	已出版 - 1 12月 2009
已对外发布	是

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@article{bcb333ecd96540959ad66cabc9306504,

title = "Syntheses, structures and magnetic properties of heterobimetallic complexes based on a new tetracyanometalate precursor",

abstract = "A new mononuclear tetracyanometallic complex, (n-Bu4N)[(dbphen)Fe(CN)4] (1, dbphen = 5,6-dibromo-1,10-phenanthroline), has been prepared by reacting [(dbphen)FeII(py)2(SCN)2] and KCN in water and further oxidized with chlorine. With the use of 1 as building block, two trinuclear Fe2M complexes, [(dbphen)2Fe2(CN)8Cu(Me3tacn )]·3H2O (2), [(dbphen)2Fe2(CN)8Ni(dabhctd)]·2 H2O (3) and a chain complex of squares [(dbphen)2Fe2(CN)8Co(MeOH)2] n (4), have been synthesized and structurally characterized. Magnetic studies show ferromagnetic coupling between FeIII and MII (M = Cu, 2; Ni, 3) ions bridged by cyanides in complexes 2 and 3, while complex 4 exhibits meta-magnetic behavior.",

keywords = "Crystal structures, Cyano-bridged complexes, Heterobimetallic chains, Magnetic properties, Tetracyanometalate",

author = "Kang, {Ling Chen} and Xin Chen and Wang, {Cai Feng} and Zhou, {Xin Hui} and Zuo, {Jing Lin} and You, {Xiao Zeng}",

year = "2009",

month = dec,

day = "1",

doi = "10.1016/j.ica.2009.09.027",

language = "英语",

volume = "362",

pages = "5195--5202",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Syntheses, structures and magnetic properties of heterobimetallic complexes based on a new tetracyanometalate precursor

AU - Kang, Ling Chen

AU - Chen, Xin

AU - Wang, Cai Feng

AU - Zhou, Xin Hui

AU - Zuo, Jing Lin

AU - You, Xiao Zeng

PY - 2009/12/1

Y1 - 2009/12/1

N2 - A new mononuclear tetracyanometallic complex, (n-Bu4N)[(dbphen)Fe(CN)4] (1, dbphen = 5,6-dibromo-1,10-phenanthroline), has been prepared by reacting [(dbphen)FeII(py)2(SCN)2] and KCN in water and further oxidized with chlorine. With the use of 1 as building block, two trinuclear Fe2M complexes, [(dbphen)2Fe2(CN)8Cu(Me3tacn )]·3H2O (2), [(dbphen)2Fe2(CN)8Ni(dabhctd)]·2 H2O (3) and a chain complex of squares [(dbphen)2Fe2(CN)8Co(MeOH)2] n (4), have been synthesized and structurally characterized. Magnetic studies show ferromagnetic coupling between FeIII and MII (M = Cu, 2; Ni, 3) ions bridged by cyanides in complexes 2 and 3, while complex 4 exhibits meta-magnetic behavior.

AB - A new mononuclear tetracyanometallic complex, (n-Bu4N)[(dbphen)Fe(CN)4] (1, dbphen = 5,6-dibromo-1,10-phenanthroline), has been prepared by reacting [(dbphen)FeII(py)2(SCN)2] and KCN in water and further oxidized with chlorine. With the use of 1 as building block, two trinuclear Fe2M complexes, [(dbphen)2Fe2(CN)8Cu(Me3tacn )]·3H2O (2), [(dbphen)2Fe2(CN)8Ni(dabhctd)]·2 H2O (3) and a chain complex of squares [(dbphen)2Fe2(CN)8Co(MeOH)2] n (4), have been synthesized and structurally characterized. Magnetic studies show ferromagnetic coupling between FeIII and MII (M = Cu, 2; Ni, 3) ions bridged by cyanides in complexes 2 and 3, while complex 4 exhibits meta-magnetic behavior.

KW - Crystal structures

KW - Cyano-bridged complexes

KW - Heterobimetallic chains

KW - Magnetic properties

KW - Tetracyanometalate

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U2 - 10.1016/j.ica.2009.09.027

DO - 10.1016/j.ica.2009.09.027

M3 - 文章

AN - SCOPUS:71849113106

SN - 0020-1693

VL - 362

SP - 5195

EP - 5202

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 15

ER -

Syntheses, structures and magnetic properties of heterobimetallic complexes based on a new tetracyanometalate precursor

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