Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

Guang Xiang Liu; Kun Zhu; Sadafumi Nishihara; Rong Yi Huang; Xiao Ming Ren

doi:10.1016/j.ica.2009.09.014

Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

Guang Xiang Liu, Kun Zhu, Sadafumi Nishihara, Rong Yi Huang, Xiao Ming Ren

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35 引用（Scopus）

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Hydrothermal reaction of Zn(NO₃)₂·6H₂O with benzene-1,2,3-tricarboxylic acid (H₃BTC) or 5-bromoisophthalic acid (H₂BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn₂(OH)(BTC) (bix)]·H₂O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (4²·6)(4²·6³·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.

源语言	英语
页（从-至）	5103-5108
页数	6
期刊	Inorganica Chimica Acta
卷	362
期	14
DOI	https://doi.org/10.1016/j.ica.2009.09.014
出版状态	已出版 - 10 11月 2009
已对外发布	是

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title = "Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene",

abstract = "Hydrothermal reaction of Zn(NO3)2·6H2O with benzene-1,2,3-tricarboxylic acid (H3BTC) or 5-bromoisophthalic acid (H2BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn2(OH)(BTC) (bix)]·H2O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (42·6)(42·63·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.",

keywords = "Coordination polymer, Luminescence, Polycarboxylate, Zinc",

author = "Liu, {Guang Xiang} and Kun Zhu and Sadafumi Nishihara and Huang, {Rong Yi} and Ren, {Xiao Ming}",

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T1 - Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

AU - Liu, Guang Xiang

AU - Zhu, Kun

AU - Nishihara, Sadafumi

AU - Huang, Rong Yi

AU - Ren, Xiao Ming

PY - 2009/11/10

Y1 - 2009/11/10

N2 - Hydrothermal reaction of Zn(NO3)2·6H2O with benzene-1,2,3-tricarboxylic acid (H3BTC) or 5-bromoisophthalic acid (H2BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn2(OH)(BTC) (bix)]·H2O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (42·6)(42·63·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.

AB - Hydrothermal reaction of Zn(NO3)2·6H2O with benzene-1,2,3-tricarboxylic acid (H3BTC) or 5-bromoisophthalic acid (H2BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn2(OH)(BTC) (bix)]·H2O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (42·6)(42·63·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.

KW - Coordination polymer

KW - Luminescence

KW - Polycarboxylate

KW - Zinc

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Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

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