TY - JOUR
T1 - Synthesis, crystal structure and luminescent property of one-dimensional chain complex [Cd(FA)(pyim)(H 2O)]
AU - Kong, Xue Jun
AU - Zhu, Kun
AU - Kai, Tian Han
AU - Liu, Guang Xiang
AU - Ren, Xiao Ming
PY - 2009/12
Y1 - 2009/12
N2 - A one-dimensional zigzag chain complex of Cd(FA)(pyim)(H 2O) (l) (H 2FA=4, 4'-(hexafluoroisopropylid-ene)bis(benzoic acid) and pyim=2-(2-pyridyl)imidazole) was hydrothermal synthesized from Cd(NO 3) 2·4H 2O, 4, 4'- (hexafluoroisopropylidene)bis (benzoic acid) and 2-(2-pyridyl)imidazole. Single-crystal X-ray analysis revealed that the zigzag chains of 1 are linked into three-dimensional supramolecular networks by both O -H · · · O hydrogen-bonds and π...π stacking interactions. The crystal is of monoclinic, space group P2Jn with a=0.856 34(10) nm, b = 1.02049(12) nm, c=2.809 0(3) nm, ß=98.115(2)°, V=2.4302(5) nm 3, D c= 1.820 g·cm -3, Z=4, F(000)=1 320, Goof= 1.009, R 1 =0.047 0, wR 2 =0.115 5. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 733837.
AB - A one-dimensional zigzag chain complex of Cd(FA)(pyim)(H 2O) (l) (H 2FA=4, 4'-(hexafluoroisopropylid-ene)bis(benzoic acid) and pyim=2-(2-pyridyl)imidazole) was hydrothermal synthesized from Cd(NO 3) 2·4H 2O, 4, 4'- (hexafluoroisopropylidene)bis (benzoic acid) and 2-(2-pyridyl)imidazole. Single-crystal X-ray analysis revealed that the zigzag chains of 1 are linked into three-dimensional supramolecular networks by both O -H · · · O hydrogen-bonds and π...π stacking interactions. The crystal is of monoclinic, space group P2Jn with a=0.856 34(10) nm, b = 1.02049(12) nm, c=2.809 0(3) nm, ß=98.115(2)°, V=2.4302(5) nm 3, D c= 1.820 g·cm -3, Z=4, F(000)=1 320, Goof= 1.009, R 1 =0.047 0, wR 2 =0.115 5. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 733837.
KW - Cadmium(II) complex
KW - Crystal structure
KW - Flexible carboxylate ligand
KW - Photoluminescent property
UR - http://www.scopus.com/inward/record.url?scp=72249100643&partnerID=8YFLogxK
M3 - 文章
AN - SCOPUS:72249100643
SN - 1001-4861
VL - 25
SP - 2193
EP - 2196
JO - Chinese Journal of Inorganic Chemistry
JF - Chinese Journal of Inorganic Chemistry
IS - 12
ER -