Synthesis, Crystal Structure of Complex of (NO 2Ql) 2[Ni(mnt) 2]

Hai Fan Li; Xiao Ming Ren; Qing Jin Meng

Synthesis, Crystal Structure of Complex of (NO ₂Ql) ₂[Ni(mnt) ₂]

Hai Fan Li, Xiao Ming Ren, Qing Jin Meng

Nanjing University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

The ion-pair complex (NO ₂Ql) ₂[Ni(mnt) ₂] ((NO ₂Ql) ⁺ = 1-(4-nitrobenzyl) -quilorinium; mnt ^2- = maleonitriledithiolate) has been prepared, characterized by elementary analysis and IR spectrum. The crystal structure determination of this complex shows: Triclinic, space group P1̄ with a = 8.2240(16) Å, b = 10.777(2) Å, c = 12. 137(2) Å, α = 72.58(3)°, β = 72. 82(3)°, γ = 68. 78(3)°, V = 935. 4(3) Å3 and Z = 1. The most prominent general structural features of the complex are the completely segregated stack columns of [Ni(mnt) ₂] ^2- anions and [NO ₂Ql] ⁺ cations. The [Ni(mnt) ₂] ^2- anions form uniform one-dimensional chain within the anion column, and there are weak π ^...π stacking interactions between neighbor cations.

源语言	英语
页（从-至）	x17-561
期刊	Chinese Journal of Inorganic Chemistry
卷	17
期	4
出版状态	已出版 - 2001
已对外发布	是

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@article{57e32a78e2564f619049576e41483454,

title = "Synthesis, Crystal Structure of Complex of (NO 2Ql) 2[Ni(mnt) 2]",

abstract = "The ion-pair complex (NO 2Ql) 2[Ni(mnt) 2] ((NO 2Ql) + = 1-(4-nitrobenzyl) -quilorinium; mnt 2- = maleonitriledithiolate) has been prepared, characterized by elementary analysis and IR spectrum. The crystal structure determination of this complex shows: Triclinic, space group P{\=1} with a = 8.2240(16) {\AA}, b = 10.777(2) {\AA}, c = 12. 137(2) {\AA}, α = 72.58(3)°, β = 72. 82(3)°, γ = 68. 78(3)°, V = 935. 4(3) {\AA}3 and Z = 1. The most prominent general structural features of the complex are the completely segregated stack columns of [Ni(mnt) 2] 2- anions and [NO 2Ql] + cations. The [Ni(mnt) 2] 2- anions form uniform one-dimensional chain within the anion column, and there are weak π ...π stacking interactions between neighbor cations.",

keywords = "Crystal structure, Maleonitriledithiolate complex, Synthesis",

author = "Li, {Hai Fan} and Ren, {Xiao Ming} and Meng, {Qing Jin}",

year = "2001",

language = "英语",

volume = "17",

pages = "x17--561",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "4",

}

TY - JOUR

T1 - Synthesis, Crystal Structure of Complex of (NO 2Ql) 2[Ni(mnt) 2]

AU - Li, Hai Fan

AU - Ren, Xiao Ming

AU - Meng, Qing Jin

PY - 2001

Y1 - 2001

N2 - The ion-pair complex (NO 2Ql) 2[Ni(mnt) 2] ((NO 2Ql) + = 1-(4-nitrobenzyl) -quilorinium; mnt 2- = maleonitriledithiolate) has been prepared, characterized by elementary analysis and IR spectrum. The crystal structure determination of this complex shows: Triclinic, space group P1̄ with a = 8.2240(16) Å, b = 10.777(2) Å, c = 12. 137(2) Å, α = 72.58(3)°, β = 72. 82(3)°, γ = 68. 78(3)°, V = 935. 4(3) Å3 and Z = 1. The most prominent general structural features of the complex are the completely segregated stack columns of [Ni(mnt) 2] 2- anions and [NO 2Ql] + cations. The [Ni(mnt) 2] 2- anions form uniform one-dimensional chain within the anion column, and there are weak π ...π stacking interactions between neighbor cations.

AB - The ion-pair complex (NO 2Ql) 2[Ni(mnt) 2] ((NO 2Ql) + = 1-(4-nitrobenzyl) -quilorinium; mnt 2- = maleonitriledithiolate) has been prepared, characterized by elementary analysis and IR spectrum. The crystal structure determination of this complex shows: Triclinic, space group P1̄ with a = 8.2240(16) Å, b = 10.777(2) Å, c = 12. 137(2) Å, α = 72.58(3)°, β = 72. 82(3)°, γ = 68. 78(3)°, V = 935. 4(3) Å3 and Z = 1. The most prominent general structural features of the complex are the completely segregated stack columns of [Ni(mnt) 2] 2- anions and [NO 2Ql] + cations. The [Ni(mnt) 2] 2- anions form uniform one-dimensional chain within the anion column, and there are weak π ...π stacking interactions between neighbor cations.

KW - Crystal structure

KW - Maleonitriledithiolate complex

KW - Synthesis

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M3 - 文章

AN - SCOPUS:0345856612

SN - 1001-4861

VL - 17

SP - x17-561

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 4

ER -

Synthesis, Crystal Structure of Complex of (NO 2Ql) 2[Ni(mnt) 2]

摘要

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引用此

Synthesis, Crystal Structure of Complex of (NO ₂Ql) ₂[Ni(mnt) ₂]