Synthesis, crystal structures, and magnetic properties of three iron(II) complexes with 3-(p -bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2,4-triazole

Xin He; Dong Yong Cao; Jing Jing Jiang; Xuan Shen; Dun Ru Zhu

doi:10.1080/00958972.2013.877585

Synthesis, crystal structures, and magnetic properties of three iron(II) complexes with 3-(p -bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2,4-triazole

Xin He, Dong Yong Cao, Jing Jing Jiang, Xuan Shen, Dun Ru Zhu

化工学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

Three iron(II) complexes with 3-(p-bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2, 4-triazole (L), trans-[FeL₂(NCS)₂] (1), trans-[FeL ₂(NCS)₂]·2MeOH (1·2MeOH), and trans-[FeL₂(NCSe)₂] (2), have been synthesized and characterized by elemental analysis, FT-IR, ESI-MS, and single crystal X-ray crystallography. Crystallographic studies reveal that all the complexes contain a distorted octahedral [FeN₆] core with two trans NCS(Se)^- ions. Each L adopts a chelating bidentate coordination via one N of pyridyl and one N of triazole. Magnetic susceptibility measurement indicated that both 1 and 1·2MeOH are in a high-spin state from 2 to 300 K.

源语言	英语
页（从-至）	227-235
页数	9
期刊	Journal of Coordination Chemistry
卷	67
期	2
DOI	https://doi.org/10.1080/00958972.2013.877585
出版状态	已出版 - 17 1月 2014

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title = "Synthesis, crystal structures, and magnetic properties of three iron(II) complexes with 3-(p -bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2,4-triazole",

abstract = "Three iron(II) complexes with 3-(p-bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2, 4-triazole (L), trans-[FeL2(NCS)2] (1), trans-[FeL 2(NCS)2]·2MeOH (1·2MeOH), and trans-[FeL2(NCSe)2] (2), have been synthesized and characterized by elemental analysis, FT-IR, ESI-MS, and single crystal X-ray crystallography. Crystallographic studies reveal that all the complexes contain a distorted octahedral [FeN6] core with two trans NCS(Se)- ions. Each L adopts a chelating bidentate coordination via one N of pyridyl and one N of triazole. Magnetic susceptibility measurement indicated that both 1 and 1·2MeOH are in a high-spin state from 2 to 300 K.",

keywords = "Crystal structure, Iron(II) complex, Synthesis, Triazole",

author = "Xin He and Cao, {Dong Yong} and Jiang, {Jing Jing} and Xuan Shen and Zhu, {Dun Ru}",

year = "2014",

month = jan,

day = "17",

doi = "10.1080/00958972.2013.877585",

language = "英语",

volume = "67",

pages = "227--235",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

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TY - JOUR

T1 - Synthesis, crystal structures, and magnetic properties of three iron(II) complexes with 3-(p -bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2,4-triazole

AU - He, Xin

AU - Cao, Dong Yong

AU - Jiang, Jing Jing

AU - Shen, Xuan

AU - Zhu, Dun Ru

PY - 2014/1/17

Y1 - 2014/1/17

N2 - Three iron(II) complexes with 3-(p-bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2, 4-triazole (L), trans-[FeL2(NCS)2] (1), trans-[FeL 2(NCS)2]·2MeOH (1·2MeOH), and trans-[FeL2(NCSe)2] (2), have been synthesized and characterized by elemental analysis, FT-IR, ESI-MS, and single crystal X-ray crystallography. Crystallographic studies reveal that all the complexes contain a distorted octahedral [FeN6] core with two trans NCS(Se)- ions. Each L adopts a chelating bidentate coordination via one N of pyridyl and one N of triazole. Magnetic susceptibility measurement indicated that both 1 and 1·2MeOH are in a high-spin state from 2 to 300 K.

AB - Three iron(II) complexes with 3-(p-bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2, 4-triazole (L), trans-[FeL2(NCS)2] (1), trans-[FeL 2(NCS)2]·2MeOH (1·2MeOH), and trans-[FeL2(NCSe)2] (2), have been synthesized and characterized by elemental analysis, FT-IR, ESI-MS, and single crystal X-ray crystallography. Crystallographic studies reveal that all the complexes contain a distorted octahedral [FeN6] core with two trans NCS(Se)- ions. Each L adopts a chelating bidentate coordination via one N of pyridyl and one N of triazole. Magnetic susceptibility measurement indicated that both 1 and 1·2MeOH are in a high-spin state from 2 to 300 K.

KW - Crystal structure

KW - Iron(II) complex

KW - Synthesis

KW - Triazole

UR - http://www.scopus.com/inward/record.url?scp=84897597277&partnerID=8YFLogxK

U2 - 10.1080/00958972.2013.877585

DO - 10.1080/00958972.2013.877585

M3 - 文章

AN - SCOPUS:84897597277

SN - 0095-8972

VL - 67

SP - 227

EP - 235

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 2

ER -

Synthesis, crystal structures, and magnetic properties of three iron(II) complexes with 3-(p -bromophenyl)-4-phenyl-5-(2-pyridyl)-1,2,4-triazole

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