TY - JOUR
T1 - Synthesis, structure and physical properties of the one-dimensional chain complex of tetrathiafulvalene carboxylate
AU - Chen, Ya
AU - Li, Chenghui
AU - Wang, Caifeng
AU - Wu, Di
AU - Zuo, Jinglin
AU - You, Xiaozeng
PY - 2009/10
Y1 - 2009/10
N2 - A new Co(II) coordination polymer bearing TTF carboxylate group, [{Co 2(trioTTF)2(H2O)6}•5H 2O]n (1) (trioTTF = 2-(5,6,8,9,11,12,14,15-octahydro-[1,3] dithiolo[4,5-h][1,4,13,7,10]trioxadithiacyclopentadecin-2-ylidene)-1, 3-dithiole-4,5-dicarboxylate), has been prepared and characterized. In the structure of 1, shorter intermolecular S••••S contacts (3.565 Å) are found between the trioTTF groups from neighboring chains. The electric conductivity of 1 is poor due to the bulky crown-ether group, but it exhibits ferromagnetic interaction at low temperature.
AB - A new Co(II) coordination polymer bearing TTF carboxylate group, [{Co 2(trioTTF)2(H2O)6}•5H 2O]n (1) (trioTTF = 2-(5,6,8,9,11,12,14,15-octahydro-[1,3] dithiolo[4,5-h][1,4,13,7,10]trioxadithiacyclopentadecin-2-ylidene)-1, 3-dithiole-4,5-dicarboxylate), has been prepared and characterized. In the structure of 1, shorter intermolecular S••••S contacts (3.565 Å) are found between the trioTTF groups from neighboring chains. The electric conductivity of 1 is poor due to the bulky crown-ether group, but it exhibits ferromagnetic interaction at low temperature.
KW - Cobalt complexes
KW - Crystal structures
KW - Syntheses
KW - Tetrathiafulvalene
UR - http://www.scopus.com/inward/record.url?scp=70350234885&partnerID=8YFLogxK
U2 - 10.1007/s11426-009-0237-2
DO - 10.1007/s11426-009-0237-2
M3 - 文章
AN - SCOPUS:70350234885
SN - 1006-9291
VL - 52
SP - 1596
EP - 1601
JO - Science in China, Series B: Chemistry
JF - Science in China, Series B: Chemistry
IS - 10
ER -