Synthesis, structure and properties of the first organic amine-templated vanadyl pyrophosphate containing two types of helical chains

Hong Xiang Wan; Wen Tao Hou; Wei Wei Ju; Yu Zhang; Hao Miao; You Song; Yan Xu

doi:10.1016/j.inoche.2014.04.019

Synthesis, structure and properties of the first organic amine-templated vanadyl pyrophosphate containing two types of helical chains

Hong Xiang Wan, Wen Tao Hou, Wei Wei Ju, Yu Zhang, Hao Miao, You Song, Yan Xu

材料科学与工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

The first organic amine templated vanadyl pyrophosphate, [H ₂N(CH₃)₂]₂VO(P₂O ₇) (1), has been synthesized at a relatively mild temperature (180 °C) under solvothermal conditions without any pyrophosphates. The structural analysis reveals that compound 1 is constructed by two types of helical chains and protonated dimethylamine cations. Two types of helical chains in 1 are connected through OVO linkages to make a double wave-like [VOP₂O ₇]_n chain. Magnetic susceptibility measurement of compound 1 indicates antiferromagnetic interactions between V^{4 +} ions, while the observed SHG efficiency is 0.4 times of urea for 1.

源语言	英语
页（从-至）	120-123
页数	4
期刊	Inorganic Chemistry Communications
卷	45
DOI	https://doi.org/10.1016/j.inoche.2014.04.019
出版状态	已出版 - 7月 2014

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10.1016/j.inoche.2014.04.019

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title = "Synthesis, structure and properties of the first organic amine-templated vanadyl pyrophosphate containing two types of helical chains",

abstract = "The first organic amine templated vanadyl pyrophosphate, [H 2N(CH3)2]2VO(P2O 7) (1), has been synthesized at a relatively mild temperature (180 °C) under solvothermal conditions without any pyrophosphates. The structural analysis reveals that compound 1 is constructed by two types of helical chains and protonated dimethylamine cations. Two types of helical chains in 1 are connected through OVO linkages to make a double wave-like [VOP2O 7]n chain. Magnetic susceptibility measurement of compound 1 indicates antiferromagnetic interactions between V4 + ions, while the observed SHG efficiency is 0.4 times of urea for 1.",

keywords = "Helical chain, Magnetic property, Polyoxovanadate, Pyrophosphate, Structure",

author = "Wan, {Hong Xiang} and Hou, {Wen Tao} and Ju, {Wei Wei} and Yu Zhang and Hao Miao and You Song and Yan Xu",

year = "2014",

month = jul,

doi = "10.1016/j.inoche.2014.04.019",

language = "英语",

volume = "45",

pages = "120--123",

journal = "Inorganic Chemistry Communications",

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T1 - Synthesis, structure and properties of the first organic amine-templated vanadyl pyrophosphate containing two types of helical chains

AU - Wan, Hong Xiang

AU - Hou, Wen Tao

AU - Ju, Wei Wei

AU - Zhang, Yu

AU - Miao, Hao

AU - Song, You

AU - Xu, Yan

PY - 2014/7

Y1 - 2014/7

N2 - The first organic amine templated vanadyl pyrophosphate, [H 2N(CH3)2]2VO(P2O 7) (1), has been synthesized at a relatively mild temperature (180 °C) under solvothermal conditions without any pyrophosphates. The structural analysis reveals that compound 1 is constructed by two types of helical chains and protonated dimethylamine cations. Two types of helical chains in 1 are connected through OVO linkages to make a double wave-like [VOP2O 7]n chain. Magnetic susceptibility measurement of compound 1 indicates antiferromagnetic interactions between V4 + ions, while the observed SHG efficiency is 0.4 times of urea for 1.

AB - The first organic amine templated vanadyl pyrophosphate, [H 2N(CH3)2]2VO(P2O 7) (1), has been synthesized at a relatively mild temperature (180 °C) under solvothermal conditions without any pyrophosphates. The structural analysis reveals that compound 1 is constructed by two types of helical chains and protonated dimethylamine cations. Two types of helical chains in 1 are connected through OVO linkages to make a double wave-like [VOP2O 7]n chain. Magnetic susceptibility measurement of compound 1 indicates antiferromagnetic interactions between V4 + ions, while the observed SHG efficiency is 0.4 times of urea for 1.

KW - Helical chain

KW - Magnetic property

KW - Polyoxovanadate

KW - Pyrophosphate

KW - Structure

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U2 - 10.1016/j.inoche.2014.04.019

DO - 10.1016/j.inoche.2014.04.019

M3 - 文章

AN - SCOPUS:84901267587

SN - 1387-7003

VL - 45

SP - 120

EP - 123

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis, structure and properties of the first organic amine-templated vanadyl pyrophosphate containing two types of helical chains

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