Two homochiral organocatalytic metal organic materials with nanoscopic channels

Zhuxiu Zhang; Young Ran Ji; Lukasz Wojtas; Wen Yang Gao; Shengqian Ma; Michael J. Zaworotko; Jon C. Antilla

doi:10.1039/c3cc43801e

Two homochiral organocatalytic metal organic materials with nanoscopic channels

Zhuxiu Zhang, Young Ran Ji, Lukasz Wojtas, Wen Yang Gao, Shengqian Ma, Michael J. Zaworotko, Jon C. Antilla

University of South Florida

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55 引用（Scopus）

摘要

Two homochiral organocatalytic MOMs were prepared using tetra- and octa-carboxylate ligands, respectively. The nanoscopic channels in these MOMs are lined by organonocatalytic chiral phosphoric acid derivatives of binol and ocMOM-1 exhibited improved enantioselectivity over the parent ligand in the context of transfer hydrogenation of a series of benzoxazines.

源语言	英语
页（从-至）	7693-7695
页数	3
期刊	Chemical Communications
卷	49
期	70
DOI	https://doi.org/10.1039/c3cc43801e
出版状态	已出版 - 6 8月 2013
已对外发布	是

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AU - Zhang, Zhuxiu

AU - Ji, Young Ran

AU - Wojtas, Lukasz

AU - Gao, Wen Yang

AU - Ma, Shengqian

AU - Zaworotko, Michael J.

AU - Antilla, Jon C.

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AB - Two homochiral organocatalytic MOMs were prepared using tetra- and octa-carboxylate ligands, respectively. The nanoscopic channels in these MOMs are lined by organonocatalytic chiral phosphoric acid derivatives of binol and ocMOM-1 exhibited improved enantioselectivity over the parent ligand in the context of transfer hydrogenation of a series of benzoxazines.

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Two homochiral organocatalytic metal organic materials with nanoscopic channels

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