Visible-light-induced methylsulfonylation/bicyclization of C(sp3)-tethered 1,7-enynes using a DMSO/H2O system

Min Hua Huang, Chi Fan Zhu, Chun Lan He, Yi Long Zhu, Wen Juan Hao, De Cai Wang, Shu Jiang Tu, Bo Jiang

科研成果: 期刊稿件文章同行评审

56 引用 (Scopus)

摘要

A visible light photocatalytic methylsulfonylation/bicyclization of C(sp3)-tethered 1,7-enynes has been established using a dimethyl sulfoxide (DMSO)/H2O system as the methylsulfonyl source. This reaction worked readily to access a wide range of sulfone-containing benzo[a]fluoren-5-ones with one quaternary carbon centre and generally good yields through C-S bond cleavage of DMSO. The reaction mechanism was proposed based on the control experiments.

源语言英语
页(从-至)1643-1650
页数8
期刊Organic Chemistry Frontiers
5
10
DOI
出版状态已出版 - 21 5月 2018

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