{[VIV14VV4O42(H 2O)][Ni(C4N3H13)(C4N 3H14)]4(H2O)6} 4+: A novel nanosized calix-type polyoxovanadate cation

Zhibin Zhang, Yan Xu, Lei Zheng, Dunru Zhu, You Song

科研成果: 期刊稿件文章同行评审

13 引用 (Scopus)

摘要

An organic-inorganic hybrid solid material (C4N 3H16)2{[VIV14V V4O42(H2O)][Ni(C4N 3H13)(C4N3H14)] 4(H2O)6}[HVIV14V V4O42(PO4)] 1 which is constructed from a novel nanosized calix-type polyoxovanadate {[VIV 14VV4O42(H2O)][Ni(C 4N3H13)(C4N3H 14)]4(H2O)6}4+ cation and a hexa-capping Keggin structural anion [HVIV14V V4O42(PO4)]10- has been synthesized. Structural analysis indicates the nanosized calix-type V-O-Ni cluster cation is filled with six water molecules.

源语言英语
页(从-至)2191-2193
页数3
期刊CrystEngComm
13
7
DOI
出版状态已出版 - 7 4月 2011

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