2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its dication spectroelectrochemistry and model calculations on a dioxa-22-π-system

Gernot Frenking; Anton Rieker; Josef Salbeck; Bernd Speiser

doi:10.1515/znb-1996-0313

2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its dication spectroelectrochemistry and model calculations on a dioxa-22-π-system

Gernot Frenking, Anton Rieker, Josef Salbeck, Bernd Speiser

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Spectroelectrochemistry of 2,5,8,11-tetra-tert-butyl-peri-xanthenoxanthene 1 yields the UV/VIS spectra of the corresponding radical cation 1⁺ and dication 1²⁺. The bathochromic shift for the dication 1²⁺ relative to 1 and to the isoelectronic hydrocarbon anthanthrene (2) can be understood by quantum mechanical calculations (ab initio, AM1) of model structures.

Original language	English
Pages (from-to)	377-380
Number of pages	4
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	51
Issue number	3
DOIs	https://doi.org/10.1515/znb-1996-0313
State	Published - Mar 1996
Externally published	Yes

Keywords

Dication
MO-calculations
Radical cation
Spectroelectrochemistry
Xanthenoxanthenes

Access to Document

10.1515/znb-1996-0313

Cite this

@article{80ebb44c5a654a3ca50fcd12adcb75ef,

title = "2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its dication spectroelectrochemistry and model calculations on a dioxa-22-π-system",

abstract = "Spectroelectrochemistry of 2,5,8,11-tetra-tert-butyl-peri-xanthenoxanthene 1 yields the UV/VIS spectra of the corresponding radical cation 1+ and dication 12+. The bathochromic shift for the dication 12+ relative to 1 and to the isoelectronic hydrocarbon anthanthrene (2) can be understood by quantum mechanical calculations (ab initio, AM1) of model structures.",

keywords = "Dication, MO-calculations, Radical cation, Spectroelectrochemistry, Xanthenoxanthenes",

author = "Gernot Frenking and Anton Rieker and Josef Salbeck and Bernd Speiser",

year = "1996",

month = mar,

doi = "10.1515/znb-1996-0313",

language = "英语",

volume = "51",

pages = "377--380",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "3",

}

2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its dication spectroelectrochemistry and model calculations on a dioxa-22-π-system. / Frenking, Gernot; Rieker, Anton; Salbeck, Josef et al.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 51, No. 3, 03.1996, p. 377-380.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - 2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its dication spectroelectrochemistry and model calculations on a dioxa-22-π-system

AU - Frenking, Gernot

AU - Rieker, Anton

AU - Salbeck, Josef

AU - Speiser, Bernd

PY - 1996/3

Y1 - 1996/3

N2 - Spectroelectrochemistry of 2,5,8,11-tetra-tert-butyl-peri-xanthenoxanthene 1 yields the UV/VIS spectra of the corresponding radical cation 1+ and dication 12+. The bathochromic shift for the dication 12+ relative to 1 and to the isoelectronic hydrocarbon anthanthrene (2) can be understood by quantum mechanical calculations (ab initio, AM1) of model structures.

AB - Spectroelectrochemistry of 2,5,8,11-tetra-tert-butyl-peri-xanthenoxanthene 1 yields the UV/VIS spectra of the corresponding radical cation 1+ and dication 12+. The bathochromic shift for the dication 12+ relative to 1 and to the isoelectronic hydrocarbon anthanthrene (2) can be understood by quantum mechanical calculations (ab initio, AM1) of model structures.

KW - Dication

KW - MO-calculations

KW - Radical cation

KW - Spectroelectrochemistry

KW - Xanthenoxanthenes

UR - http://www.scopus.com/inward/record.url?scp=0040653617&partnerID=8YFLogxK

U2 - 10.1515/znb-1996-0313

DO - 10.1515/znb-1996-0313

M3 - 文章

AN - SCOPUS:0040653617

SN - 0932-0776

VL - 51

SP - 377

EP - 380

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 3

ER -

2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its dication spectroelectrochemistry and model calculations on a dioxa-22-π-system

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this