2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its dication spectroelectrochemistry and model calculations on a dioxa-22-π-system

Gernot Frenking, Anton Rieker, Josef Salbeck, Bernd Speiser

科研成果: 期刊稿件文章同行评审

4 引用 (Scopus)

摘要

Spectroelectrochemistry of 2,5,8,11-tetra-tert-butyl-peri-xanthenoxanthene 1 yields the UV/VIS spectra of the corresponding radical cation 1+ and dication 12+. The bathochromic shift for the dication 12+ relative to 1 and to the isoelectronic hydrocarbon anthanthrene (2) can be understood by quantum mechanical calculations (ab initio, AM1) of model structures.

源语言英语
页(从-至)377-380
页数4
期刊Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
51
3
DOI
出版状态已出版 - 3月 1996
已对外发布

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