摘要
Spectroelectrochemistry of 2,5,8,11-tetra-tert-butyl-peri-xanthenoxanthene 1 yields the UV/VIS spectra of the corresponding radical cation 1+ and dication 12+. The bathochromic shift for the dication 12+ relative to 1 and to the isoelectronic hydrocarbon anthanthrene (2) can be understood by quantum mechanical calculations (ab initio, AM1) of model structures.
源语言 | 英语 |
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页(从-至) | 377-380 |
页数 | 4 |
期刊 | Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences |
卷 | 51 |
期 | 3 |
DOI | |
出版状态 | 已出版 - 3月 1996 |
已对外发布 | 是 |