A crystalline phosphinyl radical cation

Olivier Back; Mehmet Ali Celik; Gernot Frenking; Mohand Melaimi; Bruno Donnadieu; Guy Bertrand

doi:10.1021/ja1046846

A crystalline phosphinyl radical cation

Olivier Back, Mehmet Ali Celik, Gernot Frenking, Mohand Melaimi, Bruno Donnadieu, Guy Bertrand

Research output: Contribution to journal › Article › peer-review

159 Scopus citations

Abstract

One-electron oxidation of a readily available phosphaalkene derived from a cyclic (alkyl)(amino)carbene affords a phosphorus-centered radical cation that is indefinitely stable both in solution and in the solid state, allowing a single X-ray diffraction study to be performed. This species can be regarded as a phosphinyl radical bearing a cationic substituent or, alternatively, as a carbene-stabilized phospheniumyl radical (carbene-RP^+·).

Original language	English
Pages (from-to)	10262-10263
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	30
DOIs	https://doi.org/10.1021/ja1046846
State	Published - 4 Aug 2010
Externally published	Yes

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10.1021/ja1046846

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title = "A crystalline phosphinyl radical cation",

abstract = "One-electron oxidation of a readily available phosphaalkene derived from a cyclic (alkyl)(amino)carbene affords a phosphorus-centered radical cation that is indefinitely stable both in solution and in the solid state, allowing a single X-ray diffraction study to be performed. This species can be regarded as a phosphinyl radical bearing a cationic substituent or, alternatively, as a carbene-stabilized phospheniumyl radical (carbene-RP+·).",

author = "Olivier Back and Celik, {Mehmet Ali} and Gernot Frenking and Mohand Melaimi and Bruno Donnadieu and Guy Bertrand",

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AU - Back, Olivier

AU - Celik, Mehmet Ali

AU - Frenking, Gernot

AU - Melaimi, Mohand

AU - Donnadieu, Bruno

AU - Bertrand, Guy

PY - 2010/8/4

Y1 - 2010/8/4

N2 - One-electron oxidation of a readily available phosphaalkene derived from a cyclic (alkyl)(amino)carbene affords a phosphorus-centered radical cation that is indefinitely stable both in solution and in the solid state, allowing a single X-ray diffraction study to be performed. This species can be regarded as a phosphinyl radical bearing a cationic substituent or, alternatively, as a carbene-stabilized phospheniumyl radical (carbene-RP+·).

AB - One-electron oxidation of a readily available phosphaalkene derived from a cyclic (alkyl)(amino)carbene affords a phosphorus-centered radical cation that is indefinitely stable both in solution and in the solid state, allowing a single X-ray diffraction study to be performed. This species can be regarded as a phosphinyl radical bearing a cationic substituent or, alternatively, as a carbene-stabilized phospheniumyl radical (carbene-RP+·).

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M3 - 文章

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A crystalline phosphinyl radical cation

Abstract

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