A crystalline phosphinyl radical cation

Olivier Back; Mehmet Ali Celik; Gernot Frenking; Mohand Melaimi; Bruno Donnadieu; Guy Bertrand

doi:10.1021/ja1046846

A crystalline phosphinyl radical cation

Olivier Back, Mehmet Ali Celik, Gernot Frenking, Mohand Melaimi, Bruno Donnadieu, Guy Bertrand

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159 引用（Scopus）

摘要

One-electron oxidation of a readily available phosphaalkene derived from a cyclic (alkyl)(amino)carbene affords a phosphorus-centered radical cation that is indefinitely stable both in solution and in the solid state, allowing a single X-ray diffraction study to be performed. This species can be regarded as a phosphinyl radical bearing a cationic substituent or, alternatively, as a carbene-stabilized phospheniumyl radical (carbene-RP^+·).

源语言	英语
页（从-至）	10262-10263
页数	2
期刊	Journal of the American Chemical Society
卷	132
期	30
DOI	https://doi.org/10.1021/ja1046846
出版状态	已出版 - 4 8月 2010
已对外发布	是

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AU - Celik, Mehmet Ali

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AU - Melaimi, Mohand

AU - Donnadieu, Bruno

AU - Bertrand, Guy

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A crystalline phosphinyl radical cation

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