A multisignaling chemosensor for Hg2+ based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole

Hui Bin Sun; Shu Juan Liu; Qiang Zhao; Wei Huang

A multisignaling chemosensor for Hg²⁺ based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole

Hui Bin Sun, Shu Juan Liu, Qiang Zhao, Wei Huang

Research output: Contribution to journal › Article › peer-review

Abstract

A novel colorimetric and fluorometric chemosensor for Hg²⁺ detection is designed and synthesized based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole (PPE-BDT). A highly Hg²⁺-selective fluorescence quenching property in combination with a visible colorimetric change of solution from yellow to violet can be observed, and it shows that PPE-BDT can serve as a sensitive "naked-eye" indicator for Hg²⁺. The coordination of Hg²⁺ to the sulfur atom of benzo [2, 1, 3] thiadiazole leads to inter-chain π-π interactions, thus it is responsible for the significant variations on the photophysical properties of the polymer.

Original language	English
Pages (from-to)	128-132
Number of pages	5
Journal	Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)
Volume	34
Issue number	1
State	Published - Feb 2014
Externally published	Yes

Keywords

Conjugated polymers
Mercury
Multi-modal
Sensors

Cite this

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title = "A multisignaling chemosensor for Hg2+ based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole",

abstract = "A novel colorimetric and fluorometric chemosensor for Hg2+ detection is designed and synthesized based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole (PPE-BDT). A highly Hg2+-selective fluorescence quenching property in combination with a visible colorimetric change of solution from yellow to violet can be observed, and it shows that PPE-BDT can serve as a sensitive {"}naked-eye{"} indicator for Hg2+. The coordination of Hg2+ to the sulfur atom of benzo [2, 1, 3] thiadiazole leads to inter-chain π-π interactions, thus it is responsible for the significant variations on the photophysical properties of the polymer.",

keywords = "Conjugated polymers, Mercury, Multi-modal, Sensors",

author = "Sun, {Hui Bin} and Liu, {Shu Juan} and Qiang Zhao and Wei Huang",

year = "2014",

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language = "英语",

volume = "34",

pages = "128--132",

journal = "Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)",

issn = "1673-5439",

publisher = "Journal of Nanjing Institute of Posts and Telecommunications",

number = "1",

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A multisignaling chemosensor for Hg²⁺ based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole. / Sun, Hui Bin; Liu, Shu Juan; Zhao, Qiang et al.
In: Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science), Vol. 34, No. 1, 02.2014, p. 128-132.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A multisignaling chemosensor for Hg2+ based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole

AU - Sun, Hui Bin

AU - Liu, Shu Juan

AU - Zhao, Qiang

AU - Huang, Wei

PY - 2014/2

Y1 - 2014/2

N2 - A novel colorimetric and fluorometric chemosensor for Hg2+ detection is designed and synthesized based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole (PPE-BDT). A highly Hg2+-selective fluorescence quenching property in combination with a visible colorimetric change of solution from yellow to violet can be observed, and it shows that PPE-BDT can serve as a sensitive "naked-eye" indicator for Hg2+. The coordination of Hg2+ to the sulfur atom of benzo [2, 1, 3] thiadiazole leads to inter-chain π-π interactions, thus it is responsible for the significant variations on the photophysical properties of the polymer.

AB - A novel colorimetric and fluorometric chemosensor for Hg2+ detection is designed and synthesized based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole (PPE-BDT). A highly Hg2+-selective fluorescence quenching property in combination with a visible colorimetric change of solution from yellow to violet can be observed, and it shows that PPE-BDT can serve as a sensitive "naked-eye" indicator for Hg2+. The coordination of Hg2+ to the sulfur atom of benzo [2, 1, 3] thiadiazole leads to inter-chain π-π interactions, thus it is responsible for the significant variations on the photophysical properties of the polymer.

KW - Conjugated polymers

KW - Mercury

KW - Multi-modal

KW - Sensors

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M3 - 文章

AN - SCOPUS:84897018079

SN - 1673-5439

VL - 34

SP - 128

EP - 132

JO - Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)

JF - Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/Journal of Nanjing University of Posts and Telecommunications (Natural Science)

IS - 1

ER -

A multisignaling chemosensor for Hg²⁺ based on poly (p-phenyleneethynylene) containing benzo [2, 1, 3] thiadiazole

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Keywords

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