Active versus passive substituent participation in the auxiliary-mediated asymmetric synthesis of an octahedral metal complex

Liang An Chen; Jiajia Ma; Mehmet Ali Celik; Hong Lang Yu; Zexing Cao; Gernot Frenking; Lei Gong; Eric Meggers

doi:10.1002/asia.201200532

Active versus passive substituent participation in the auxiliary-mediated asymmetric synthesis of an octahedral metal complex

Liang An Chen, Jiajia Ma, Mehmet Ali Celik, Hong Lang Yu, Zexing Cao, Gernot Frenking, Lei Gong, Eric Meggers

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Ambiguous chirality transfer: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration or δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.

Original language	English
Pages (from-to)	2523-2526
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	7
Issue number	11
DOIs	https://doi.org/10.1002/asia.201200532
State	Published - Nov 2012
Externally published	Yes

Keywords

asymmetric synthesis
chiral auxiliary
coordination chemistry
stereocontrol
sulfur

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abstract = "Ambiguous chirality transfer: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration or δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.",

keywords = "asymmetric synthesis, chiral auxiliary, coordination chemistry, stereocontrol, sulfur",

author = "Chen, {Liang An} and Jiajia Ma and Celik, {Mehmet Ali} and Yu, {Hong Lang} and Zexing Cao and Gernot Frenking and Lei Gong and Eric Meggers",

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AU - Chen, Liang An

AU - Ma, Jiajia

AU - Celik, Mehmet Ali

AU - Yu, Hong Lang

AU - Cao, Zexing

AU - Frenking, Gernot

AU - Gong, Lei

AU - Meggers, Eric

PY - 2012/11

Y1 - 2012/11

N2 - Ambiguous chirality transfer: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration or δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.

AB - Ambiguous chirality transfer: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration or δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.

KW - asymmetric synthesis

KW - chiral auxiliary

KW - coordination chemistry

KW - stereocontrol

KW - sulfur

UR - http://www.scopus.com/inward/record.url?scp=84867480270&partnerID=8YFLogxK

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DO - 10.1002/asia.201200532

M3 - 文章

AN - SCOPUS:84867480270

SN - 1861-4728

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EP - 2526

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 11

ER -

Active versus passive substituent participation in the auxiliary-mediated asymmetric synthesis of an octahedral metal complex

Abstract

Keywords

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