Active versus passive substituent participation in the auxiliary-mediated asymmetric synthesis of an octahedral metal complex

Liang An Chen, Jiajia Ma, Mehmet Ali Celik, Hong Lang Yu, Zexing Cao, Gernot Frenking, Lei Gong, Eric Meggers

科研成果: 期刊稿件文章同行评审

10 引用 (Scopus)

摘要

Ambiguous chirality transfer: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration or δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.

源语言英语
页(从-至)2523-2526
页数4
期刊Chemistry - An Asian Journal
7
11
DOI
出版状态已出版 - 11月 2012
已对外发布

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