An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors

Bin Li; Subrata Kundu; Hongping Zhu; Helena Keil; Regine Herbst-Irmer; Dietmar Stalke; Gernot Frenking; Diego M. Andrada; Herbert W. Roesky

doi:10.1039/c7cc00325k

An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors

Bin Li, Subrata Kundu, Hongping Zhu, Helena Keil, Regine Herbst-Irmer, Dietmar Stalke, Gernot Frenking, Diego M. Andrada, Herbert W. Roesky

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The reaction of LAl: (L = HC[C(Me)N(Ar)]₂, Ar = 2,6-iPr₂C₆H₃) and cAAC:→AlX₃ (X = Cl, I) (cAAC = cyclic alkyl amino carbene) results in strikingly asymmetric Al(ii)-Al(ii) compounds LAl(X)-Al(X)₂-cAAC [X = Cl (2a); I (2b)]. In these dialuminum(ii) compounds the two Al atoms bear different ligand environments. For a detailed insight into the structures, theoretical calculations were carried out.

Original language	English
Pages (from-to)	2543-2546
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	17
DOIs	https://doi.org/10.1039/c7cc00325k
State	Published - 2017
Externally published	Yes

Access to Document

10.1039/c7cc00325k

Cite this

@article{7dbaa625c99c43a49bf7a0e7cd04f5cc,

title = "An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors",

abstract = "The reaction of LAl: (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3) and cAAC:→AlX3 (X = Cl, I) (cAAC = cyclic alkyl amino carbene) results in strikingly asymmetric Al(ii)-Al(ii) compounds LAl(X)-Al(X)2-cAAC [X = Cl (2a); I (2b)]. In these dialuminum(ii) compounds the two Al atoms bear different ligand environments. For a detailed insight into the structures, theoretical calculations were carried out.",

author = "Bin Li and Subrata Kundu and Hongping Zhu and Helena Keil and Regine Herbst-Irmer and Dietmar Stalke and Gernot Frenking and Andrada, {Diego M.} and Roesky, {Herbert W.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc00325k",

language = "英语",

volume = "53",

pages = "2543--2546",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors

AU - Li, Bin

AU - Kundu, Subrata

AU - Zhu, Hongping

AU - Keil, Helena

AU - Herbst-Irmer, Regine

AU - Stalke, Dietmar

AU - Frenking, Gernot

AU - Andrada, Diego M.

AU - Roesky, Herbert W.

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - The reaction of LAl: (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3) and cAAC:→AlX3 (X = Cl, I) (cAAC = cyclic alkyl amino carbene) results in strikingly asymmetric Al(ii)-Al(ii) compounds LAl(X)-Al(X)2-cAAC [X = Cl (2a); I (2b)]. In these dialuminum(ii) compounds the two Al atoms bear different ligand environments. For a detailed insight into the structures, theoretical calculations were carried out.

AB - The reaction of LAl: (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3) and cAAC:→AlX3 (X = Cl, I) (cAAC = cyclic alkyl amino carbene) results in strikingly asymmetric Al(ii)-Al(ii) compounds LAl(X)-Al(X)2-cAAC [X = Cl (2a); I (2b)]. In these dialuminum(ii) compounds the two Al atoms bear different ligand environments. For a detailed insight into the structures, theoretical calculations were carried out.

UR - http://www.scopus.com/inward/record.url?scp=85013893204&partnerID=8YFLogxK

U2 - 10.1039/c7cc00325k

DO - 10.1039/c7cc00325k

M3 - 文章

C2 - 28180224

AN - SCOPUS:85013893204

SN - 1359-7345

VL - 53

SP - 2543

EP - 2546

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors

Abstract

Access to Document

Other files and links

Fingerprint

Cite this