@article{7dbaa625c99c43a49bf7a0e7cd04f5cc,
title = "An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors",
abstract = "The reaction of LAl: (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3) and cAAC:→AlX3 (X = Cl, I) (cAAC = cyclic alkyl amino carbene) results in strikingly asymmetric Al(ii)-Al(ii) compounds LAl(X)-Al(X)2-cAAC [X = Cl (2a); I (2b)]. In these dialuminum(ii) compounds the two Al atoms bear different ligand environments. For a detailed insight into the structures, theoretical calculations were carried out.",
author = "Bin Li and Subrata Kundu and Hongping Zhu and Helena Keil and Regine Herbst-Irmer and Dietmar Stalke and Gernot Frenking and Andrada, {Diego M.} and Roesky, {Herbert W.}",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",
year = "2017",
doi = "10.1039/c7cc00325k",
language = "英语",
volume = "53",
pages = "2543--2546",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "17",
}