Convenient synthesis of allenylphosphoryl compounds: Via Cu-catalysed couplings of P(O)H compounds with propargyl acetates

Ruwei Shen; Bing Luo; Jianlin Yang; Lixiong Zhang; Li Biao Han

doi:10.1039/c6cc02563c

Convenient synthesis of allenylphosphoryl compounds: Via Cu-catalysed couplings of P(O)H compounds with propargyl acetates

Ruwei Shen, Bing Luo, Jianlin Yang, Lixiong Zhang, Li Biao Han

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

A novel Cu-catalysed substitution reaction of propargyl acetates with P(O)H compounds is developed to afford allenylphosphoryl compounds via C-P bond coupling in high yields under mild conditions. A plausible mechanism involving the nucleophilic interception of the Cu-allenylidene intermediates is proposed.

Original language	English
Pages (from-to)	6451-6454
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	38
DOIs	https://doi.org/10.1039/c6cc02563c
State	Published - 2016

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title = "Convenient synthesis of allenylphosphoryl compounds: Via Cu-catalysed couplings of P(O)H compounds with propargyl acetates",

abstract = "A novel Cu-catalysed substitution reaction of propargyl acetates with P(O)H compounds is developed to afford allenylphosphoryl compounds via C-P bond coupling in high yields under mild conditions. A plausible mechanism involving the nucleophilic interception of the Cu-allenylidene intermediates is proposed.",

author = "Ruwei Shen and Bing Luo and Jianlin Yang and Lixiong Zhang and Han, {Li Biao}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc02563c",

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T1 - Convenient synthesis of allenylphosphoryl compounds

T2 - Via Cu-catalysed couplings of P(O)H compounds with propargyl acetates

AU - Shen, Ruwei

AU - Luo, Bing

AU - Yang, Jianlin

AU - Zhang, Lixiong

AU - Han, Li Biao

PY - 2016

Y1 - 2016

N2 - A novel Cu-catalysed substitution reaction of propargyl acetates with P(O)H compounds is developed to afford allenylphosphoryl compounds via C-P bond coupling in high yields under mild conditions. A plausible mechanism involving the nucleophilic interception of the Cu-allenylidene intermediates is proposed.

AB - A novel Cu-catalysed substitution reaction of propargyl acetates with P(O)H compounds is developed to afford allenylphosphoryl compounds via C-P bond coupling in high yields under mild conditions. A plausible mechanism involving the nucleophilic interception of the Cu-allenylidene intermediates is proposed.

UR - http://www.scopus.com/inward/record.url?scp=84966728655&partnerID=8YFLogxK

U2 - 10.1039/c6cc02563c

DO - 10.1039/c6cc02563c

M3 - 文章

AN - SCOPUS:84966728655

SN - 1359-7345

VL - 52

SP - 6451

EP - 6454

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Convenient synthesis of allenylphosphoryl compounds: Via Cu-catalysed couplings of P(O)H compounds with propargyl acetates

Abstract

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