Convenient synthesis of allenylphosphoryl compounds: Via Cu-catalysed couplings of P(O)H compounds with propargyl acetates

Ruwei Shen, Bing Luo, Jianlin Yang, Lixiong Zhang, Li Biao Han

科研成果: 期刊稿件文章同行评审

55 引用 (Scopus)

摘要

A novel Cu-catalysed substitution reaction of propargyl acetates with P(O)H compounds is developed to afford allenylphosphoryl compounds via C-P bond coupling in high yields under mild conditions. A plausible mechanism involving the nucleophilic interception of the Cu-allenylidene intermediates is proposed.

源语言英语
页(从-至)6451-6454
页数4
期刊Chemical Communications
52
38
DOI
出版状态已出版 - 2016

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