Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes

Tanveer Ahmad; Qi Li; Sheng Qi Qiu; Jian Lin Xu; Yun He Xu; Teck Peng Loh

doi:10.1039/c9ob01086f

Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes

Tanveer Ahmad, Qi Li, Sheng Qi Qiu, Jian Lin Xu, Yun He Xu, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.

Original language	English
Pages (from-to)	6122-6126
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	17
Issue number	25
DOIs	https://doi.org/10.1039/c9ob01086f
State	Published - 2019
Externally published	Yes

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title = "Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes",

abstract = "A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.",

author = "Tanveer Ahmad and Qi Li and Qiu, {Sheng Qi} and Xu, {Jian Lin} and Xu, {Yun He} and Loh, {Teck Peng}",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9ob01086f",

language = "英语",

volume = "17",

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TY - JOUR

T1 - Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates

T2 - Access to functionalized allylsilanes

AU - Ahmad, Tanveer

AU - Li, Qi

AU - Qiu, Sheng Qi

AU - Xu, Jian Lin

AU - Xu, Yun He

AU - Loh, Teck Peng

N1 - Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.

AB - A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.

UR - http://www.scopus.com/inward/record.url?scp=85068076990&partnerID=8YFLogxK

U2 - 10.1039/c9ob01086f

DO - 10.1039/c9ob01086f

M3 - 文章

C2 - 31172157

AN - SCOPUS:85068076990

SN - 1477-0520

VL - 17

SP - 6122

EP - 6126

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 25

ER -

Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes

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