Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes

Tanveer Ahmad, Qi Li, Sheng Qi Qiu, Jian Lin Xu, Yun He Xu, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

13 引用 (Scopus)

摘要

A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.

源语言英语
页(从-至)6122-6126
页数5
期刊Organic and Biomolecular Chemistry
17
25
DOI
出版状态已出版 - 2019
已对外发布

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