Cu-Catalyzed hydrophosphorylative ring opening of propargyl epoxides: Highly selective access to 4-phosphoryl 2,3-allenols

Ruwei Shen; Jianlin Yang; Haipeng Zhao; Yu Feng; Lixiong Zhang; Li Biao Han

doi:10.1039/c6cc05428e

Cu-Catalyzed hydrophosphorylative ring opening of propargyl epoxides: Highly selective access to 4-phosphoryl 2,3-allenols

Ruwei Shen, Jianlin Yang, Haipeng Zhao, Yu Feng, Lixiong Zhang, Li Biao Han

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A novel CuI-catalyzed cross-coupling of propargyl epoxides with P(O)H compounds is disclosed. The reaction proceeded efficiently under mild conditions to give 4-phosphoryl 2,3-allenols in good to high yields with excellent selectivity. The utility of the products was demonstrated and a plausible mechanism was also proposed.

Original language	English
Pages (from-to)	11959-11962
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	80
DOIs	https://doi.org/10.1039/c6cc05428e
State	Published - 2016

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title = "Cu-Catalyzed hydrophosphorylative ring opening of propargyl epoxides: Highly selective access to 4-phosphoryl 2,3-allenols",

abstract = "A novel CuI-catalyzed cross-coupling of propargyl epoxides with P(O)H compounds is disclosed. The reaction proceeded efficiently under mild conditions to give 4-phosphoryl 2,3-allenols in good to high yields with excellent selectivity. The utility of the products was demonstrated and a plausible mechanism was also proposed.",

author = "Ruwei Shen and Jianlin Yang and Haipeng Zhao and Yu Feng and Lixiong Zhang and Han, {Li Biao}",

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year = "2016",

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volume = "52",

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journal = "Chemical Communications",

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T1 - Cu-Catalyzed hydrophosphorylative ring opening of propargyl epoxides

T2 - Highly selective access to 4-phosphoryl 2,3-allenols

AU - Shen, Ruwei

AU - Yang, Jianlin

AU - Zhao, Haipeng

AU - Feng, Yu

AU - Zhang, Lixiong

AU - Han, Li Biao

PY - 2016

Y1 - 2016

N2 - A novel CuI-catalyzed cross-coupling of propargyl epoxides with P(O)H compounds is disclosed. The reaction proceeded efficiently under mild conditions to give 4-phosphoryl 2,3-allenols in good to high yields with excellent selectivity. The utility of the products was demonstrated and a plausible mechanism was also proposed.

AB - A novel CuI-catalyzed cross-coupling of propargyl epoxides with P(O)H compounds is disclosed. The reaction proceeded efficiently under mild conditions to give 4-phosphoryl 2,3-allenols in good to high yields with excellent selectivity. The utility of the products was demonstrated and a plausible mechanism was also proposed.

UR - http://www.scopus.com/inward/record.url?scp=84989324595&partnerID=8YFLogxK

U2 - 10.1039/c6cc05428e

DO - 10.1039/c6cc05428e

M3 - 文章

AN - SCOPUS:84989324595

SN - 1359-7345

VL - 52

SP - 11959

EP - 11962

JO - Chemical Communications

JF - Chemical Communications

IS - 80

ER -

Cu-Catalyzed hydrophosphorylative ring opening of propargyl epoxides: Highly selective access to 4-phosphoryl 2,3-allenols

Abstract

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