Cu-Catalyzed hydrophosphorylative ring opening of propargyl epoxides: Highly selective access to 4-phosphoryl 2,3-allenols

Ruwei Shen, Jianlin Yang, Haipeng Zhao, Yu Feng, Lixiong Zhang, Li Biao Han

科研成果: 期刊稿件文章同行评审

28 引用 (Scopus)

摘要

A novel CuI-catalyzed cross-coupling of propargyl epoxides with P(O)H compounds is disclosed. The reaction proceeded efficiently under mild conditions to give 4-phosphoryl 2,3-allenols in good to high yields with excellent selectivity. The utility of the products was demonstrated and a plausible mechanism was also proposed.

源语言英语
页(从-至)11959-11962
页数4
期刊Chemical Communications
52
80
DOI
出版状态已出版 - 2016

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