Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

Tao Chen; Li Wang; Guohua Jiang; Jianjun Wang; Xiaochen Dong; Xuejie Wang; Junfeng Zhou; Chiliang Wang; Wei Wang

doi:10.1021/jp0461246

Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

Tao Chen, Li Wang, Guohua Jiang, Jianjun Wang, Xiaochen Dong, Xuejie Wang, Junfeng Zhou, Chiliang Wang, Wei Wang

Zhejiang University

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO₄ the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.

Original language	English
Pages (from-to)	4624-4630
Number of pages	7
Journal	Journal of Physical Chemistry B
Volume	109
Issue number	10
DOIs	https://doi.org/10.1021/jp0461246
State	Published - 17 Mar 2005
Externally published	Yes

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title = "Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films",

abstract = "The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO4 the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.",

author = "Tao Chen and Li Wang and Guohua Jiang and Jianjun Wang and Xiaochen Dong and Xuejie Wang and Junfeng Zhou and Chiliang Wang and Wei Wang",

year = "2005",

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doi = "10.1021/jp0461246",

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T1 - Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

AU - Chen, Tao

AU - Wang, Li

AU - Jiang, Guohua

AU - Wang, Jianjun

AU - Dong, Xiaochen

AU - Wang, Xuejie

AU - Zhou, Junfeng

AU - Wang, Chiliang

AU - Wang, Wei

PY - 2005/3/17

Y1 - 2005/3/17

N2 - The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO4 the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.

AB - The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO4 the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.

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U2 - 10.1021/jp0461246

DO - 10.1021/jp0461246

M3 - 文章

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SN - 1520-6106

VL - 109

SP - 4624

EP - 4630

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 10

ER -

Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

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