Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

Tao Chen; Li Wang; Guohua Jiang; Jianjun Wang; Xiaochen Dong; Xuejie Wang; Junfeng Zhou; Chiliang Wang; Wei Wang

doi:10.1021/jp0461246

Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

Tao Chen, Li Wang, Guohua Jiang, Jianjun Wang, Xiaochen Dong, Xuejie Wang, Junfeng Zhou, Chiliang Wang, Wei Wang

Zhejiang University

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

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The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO₄ the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.

源语言	英语
页（从-至）	4624-4630
页数	7
期刊	Journal of Physical Chemistry B
卷	109
期	10
DOI	https://doi.org/10.1021/jp0461246
出版状态	已出版 - 17 3月 2005
已对外发布	是

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abstract = "The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO4 the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.",

author = "Tao Chen and Li Wang and Guohua Jiang and Jianjun Wang and Xiaochen Dong and Xuejie Wang and Junfeng Zhou and Chiliang Wang and Wei Wang",

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T1 - Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

AU - Chen, Tao

AU - Wang, Li

AU - Jiang, Guohua

AU - Wang, Jianjun

AU - Dong, Xiaochen

AU - Wang, Xuejie

AU - Zhou, Junfeng

AU - Wang, Chiliang

AU - Wang, Wei

PY - 2005/3/17

Y1 - 2005/3/17

N2 - The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO4 the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.

AB - The electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO4 the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.

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DO - 10.1021/jp0461246

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Electrochemical behavior of poly(ferrocenyldimethylsilane-b- dimethylsiloxane) films

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